Chemistry
4th Edition
ISBN: 9780393919370
Author: Thomas R. Gilbert
Publisher: NORTON
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Chapter 10, Problem 10.40QP
Interpretation Introduction
Interpretation: The compound which has the higher boiling point is to be stated and explained.
Concept introduction: Boiling point of a liquid is the temperature at which vapor pressure is equal to the atmospheric pressure. Boiling point of the same liquid varies according to the surrounding conditions. For isomeric compounds the boiling points depend upon the molecular shape. The compound, which has large surface area, shows the higher boiling point than the compound which has lower surface area.
To determine: The compound which has the higher boiling point.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 10 Solutions
Chemistry
Ch. 10.1 - Prob. 1PECh. 10.2 - Prob. 2PECh. 10.3 - Prob. 3PECh. 10.4 - Prob. 4PECh. 10.4 - Prob. 5PECh. 10.5 - Prob. 6PECh. 10.6 - Prob. 7PECh. 10 - Prob. 10.1VPCh. 10 - Prob. 10.2VPCh. 10 - Prob. 10.3VP
Ch. 10 - Prob. 10.4VPCh. 10 - Prob. 10.5VPCh. 10 - Prob. 10.6VPCh. 10 - Prob. 10.8VPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Prob. 10.17QPCh. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.23QPCh. 10 - Prob. 10.24QPCh. 10 - Prob. 10.25QPCh. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.29QPCh. 10 - Prob. 10.30QPCh. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - Prob. 10.33QPCh. 10 - Prob. 10.34QPCh. 10 - Prob. 10.35QPCh. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - Prob. 10.39QPCh. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - Prob. 10.51QPCh. 10 - Prob. 10.52QPCh. 10 - Prob. 10.53QPCh. 10 - Prob. 10.54QPCh. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Prob. 10.58QPCh. 10 - Prob. 10.59QPCh. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - Prob. 10.63QPCh. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Prob. 10.67QPCh. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - Prob. 10.77QPCh. 10 - Prob. 10.78QPCh. 10 - Prob. 10.79QPCh. 10 - Prob. 10.80QPCh. 10 - Prob. 10.81QPCh. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Prob. 10.88QPCh. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Prob. 10.91QPCh. 10 - Prob. 10.92QPCh. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - Prob. 10.95QPCh. 10 - Prob. 10.96QPCh. 10 - Prob. 10.97QPCh. 10 - Prob. 10.98QPCh. 10 - Prob. 10.99APCh. 10 - Prob. 10.100APCh. 10 - Prob. 10.101APCh. 10 - Prob. 10.102APCh. 10 - Prob. 10.103APCh. 10 - Prob. 10.104APCh. 10 - Prob. 10.105APCh. 10 - Prob. 10.106APCh. 10 - Prob. 10.107APCh. 10 - Prob. 10.108APCh. 10 - Prob. 10.109APCh. 10 - Prob. 10.110APCh. 10 - Prob. 10.111APCh. 10 - Prob. 10.112APCh. 10 - Prob. 10.113APCh. 10 - Prob. 10.114APCh. 10 - Prob. 10.115APCh. 10 - Prob. 10.116APCh. 10 - Prob. 10.117APCh. 10 - Prob. 10.118APCh. 10 - Prob. 10.119APCh. 10 - Prob. 10.120APCh. 10 - Prob. 10.121AP
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