Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 10, Problem 10.22E

Though not strictly equivalent, there is a similar uncertainty relationship between the observables time and energy:

Δ E Δ t 2

In emission spectroscopy, the width of the lines (which gives a measure of Δ E ) in a spectrum can be related to the lifetime (that is, Δ t ) of the excited state. If the width of a spectral line of a certain electronic transition is 1.00 cm 1 , what is the minimum uncertainty in the lifetime of the transition? Watch your units.

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Chapter 10 Solutions

Physical Chemistry

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