Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781305717633
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 10, Problem 101AE
Interpretation Introduction
Interpretation: The molar mass of Thyroxine has to be calculated.
Concept Introduction:
Molar mass of a compound can be given by mass of a substance to the amount of the substance. It can be given by expression,
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 10 Solutions
Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 10 - Prob. 1RQCh. 10 - Using KF as an example, write equations that refer...Ch. 10 - Prob. 3RQCh. 10 - Prob. 4RQCh. 10 - Define the terms in Raoults law. Figure 10-9...Ch. 10 - In terms of Raoults law, distinguish between an...Ch. 10 - Prob. 7RQCh. 10 - Prob. 8RQCh. 10 - Prob. 9RQCh. 10 - Prob. 10RQ
Ch. 10 - Prob. 1ALQCh. 10 - Prob. 2ALQCh. 10 - Prob. 3ALQCh. 10 - Prob. 4ALQCh. 10 - You have read that adding a solute to a solvent...Ch. 10 - Prob. 6ALQCh. 10 - Prob. 7ALQCh. 10 - Prob. 8ALQCh. 10 - Prob. 9ALQCh. 10 - Prob. 10ALQCh. 10 - Rubbing alcohol contains 585 g isopropanol...Ch. 10 - Prob. 12SRCh. 10 - Prob. 13SRCh. 10 - Prob. 14SRCh. 10 - Calculate the sodium ion concentration when 70.0...Ch. 10 - Write equations showing the ions present after the...Ch. 10 - Prob. 17QCh. 10 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 10 - The two beakers in the sealed container...Ch. 10 - The following plot shows the vapor pressure of...Ch. 10 - Prob. 21QCh. 10 - Prob. 22QCh. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - Prob. 25QCh. 10 - Prob. 26QCh. 10 - Explain the terms isotonic solution, crenation,...Ch. 10 - Prob. 28QCh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Common commercial acids and bases are aqueous...Ch. 10 - In lab you need to prepare at least 100 mL of each...Ch. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Calculate the molarity and mole fraction of...Ch. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Prob. 44ECh. 10 - Prob. 45ECh. 10 - Which ion in each of the following pairs would you...Ch. 10 - Rationalize the trend in water solubility for the...Ch. 10 - Prob. 48ECh. 10 - The solubility of nitrogen in water is 8.21 104...Ch. 10 - Calculate the solubility of O2 in water at a...Ch. 10 - Glycerin, C3H8O3, is a nonvolatile liquid. What is...Ch. 10 - Prob. 52ECh. 10 - The normal boiling point of diethyl ether is...Ch. 10 - At a certain temperature, the vapor pressure of...Ch. 10 - A solution is made by dissolving 25.8 g urea...Ch. 10 - A solution of sodium chloride in water has a vapor...Ch. 10 - Prob. 57ECh. 10 - A solution is prepared by mixing 0.0300 mole of...Ch. 10 - What is the composition of a methanol...Ch. 10 - Benzene and toluene form an ideal solution....Ch. 10 - Which of the following will have the lowest total...Ch. 10 - Prob. 62ECh. 10 - Match the vapor pressure diagrams with the...Ch. 10 - The vapor pressures of several solutions of...Ch. 10 - A solution is prepared by dissolving 27.0 g urea,...Ch. 10 - A 2.00-g sample of a large biomolecule was...Ch. 10 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 10 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 10 - Prob. 69ECh. 10 - What volume of ethylene glycol (C2H6O2), a...Ch. 10 - Reserpine is a natural product isolated from the...Ch. 10 - A solution contains 3.75 g of a nonvolatile pure...Ch. 10 - a. Calculate the freezing-point depression and...Ch. 10 - Erythrocytes are red blood cells containing...Ch. 10 - Prob. 75ECh. 10 - Prob. 76ECh. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Consider the following solutions: 0.010 m Na3PO4...Ch. 10 - From the following: pure water solution of...Ch. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Consider the following representations of an ionic...Ch. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Use the following data for three aqueous solutions...Ch. 10 - The freezing-point depression of a 0.091-m...Ch. 10 - Prob. 89ECh. 10 - A 0.500-g sample of a compound is dissolved in...Ch. 10 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 10 - Prob. 92AECh. 10 - Prob. 94AECh. 10 - Explain the following on the basis of the behavior...Ch. 10 - Prob. 96AECh. 10 - Prob. 97AECh. 10 - Prob. 98AECh. 10 - A solution is made by mixing 50.0 g acetone...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - An unknown compound contains only carbon,...Ch. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Patients undergoing an upper gastrointestinal...Ch. 10 - Prob. 110CWPCh. 10 - Prob. 111CWPCh. 10 - For each of the following pairs, predict which...Ch. 10 - The normal boiling point of methanol is 64.7C. A...Ch. 10 - A solution is prepared by mixing 1.000 mole of...Ch. 10 - Prob. 115CWPCh. 10 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 10 - Prob. 117CWPCh. 10 - The vapor pressure of pure benzene is 750.0 torr...Ch. 10 - Prob. 119CPCh. 10 - Plants that thrive in salt water must have...Ch. 10 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 10 - Prob. 122CPCh. 10 - The vapor in equilibrium with a pentane-hexane...Ch. 10 - Prob. 124CPCh. 10 - Prob. 125CPCh. 10 - Prob. 126CPCh. 10 - Prob. 127CPCh. 10 - You have a solution of two volatile liquids, A and...Ch. 10 - In some regions of the southwest United States,...Ch. 10 - Prob. 130IPCh. 10 - An aqueous solution containing 0.250 mole of Q, a...Ch. 10 - Anthraquinone contains only carbon, hydrogen, and...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY