(a) Interpretation: The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

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Answer 1

Question

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

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E17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.

10.

Answer 2

Question

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

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Answer 3

Question

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

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Answer 4

Question

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

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Answer 5

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

Answer 6

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Answer 7

Chapter 10, Problem 10.16P

Interpretation Introduction

(a)

Interpretation:

The preparation of 1-iodo-4-methylpentane from an alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron-deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The preparation of (3-cyclopentylpropyl)(methyl)sulfane from alcohol and by the use of sulfonate ester methodology is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as a substitution reaction. In a nucleophilic substitution reaction, nucleophile takes the position of leaving the group by attacking on the electron-deficient carbon atom.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains how to prepare 1-iodo-4-methylpentane from an alcohol and by using sulfonate ester methodology.

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Chapter 10 Solutions