CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 10, Problem 10.145MP
An empty 4.00-Lsteel vesselis filled with 1.00 atm of CH4(g)and 4.00 atm of O2(g) at 300 °C. A spark causes the
(a) What mass of
(b) What is the final temperature inside the vessel after combustion, assuming that the steel vessel has a mass of 14.500 kg, the mixture of gases has an average molar heat capacity of
(c) What is the partial pressure of
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 10 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 10 - Hurricane Irma (2017) had a central pressure of...Ch. 10 - Prob. 10.2ACh. 10 - Prob. 10.3PCh. 10 - Prob. 10.4ACh. 10 - Conceptual PRACTICE 10.5 Show the approximate...Ch. 10 - Conceptual APPLY 10.6 Show the approximate level...Ch. 10 - How many moles of methane gas, CH4, are in a...Ch. 10 - APPLY 10.8 An aerosol spray can with a volume of...Ch. 10 - Prob. 10.9PCh. 10 - APPLY 10.10 A weather balloon has a volume of 45.0...
Ch. 10 - Prob. 10.11PCh. 10 - Prob. 10.12ACh. 10 - Prob. 10.13PCh. 10 - APPLY 10.14 The image shows carbon dioxide gas...Ch. 10 - Prob. 10.15PCh. 10 - Prob. 10.16ACh. 10 - Prob. 10.17PCh. 10 - Prob. 10.18ACh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Prob. 10.22PCh. 10 - Prob. 10.23CPCh. 10 - Prob. 10.24CPCh. 10 - Prob. 10.25CPCh. 10 - Prob. 10.26CPCh. 10 - Prob. 10.27CPCh. 10 - Prob. 10.28CPCh. 10 - Prob. 10.29CPCh. 10 - Prob. 10.30CPCh. 10 - Prob. 10.31CPCh. 10 - Prob. 10.32CPCh. 10 - Prob. 10.33CPCh. 10 - Prob. 10.34SPCh. 10 - If the density of water is 1.00 g/mL and the...Ch. 10 - Prob. 10.36SPCh. 10 - Prob. 10.37SPCh. 10 - Prob. 10.38SPCh. 10 - Carry out the following conversions: (a) 352 torr...Ch. 10 - What is the pressure in millimeters of mercury...Ch. 10 - What is the pressure in atmospheres inside a...Ch. 10 - Assume that you have an open-end manometer filled...Ch. 10 - Prob. 10.43SPCh. 10 - Prob. 10.44SPCh. 10 - Prob. 10.45SPCh. 10 - Prob. 10.46SPCh. 10 - Prob. 10.47SPCh. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Prob. 10.52SPCh. 10 - A compressed air tank carried by scuba divers has...Ch. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Prob. 10.57SPCh. 10 - Prob. 10.58SPCh. 10 - Prob. 10.59SPCh. 10 - Prob. 10.60SPCh. 10 - Prob. 10.61SPCh. 10 - Prob. 10.62SPCh. 10 - Prob. 10.63SPCh. 10 - Prob. 10.64SPCh. 10 - Prob. 10.65SPCh. 10 - Prob. 10.66SPCh. 10 - What is the density in g/L of a gas mixture that...Ch. 10 - An unknown gas is placed in a 1.500-L bulb at a...Ch. 10 - What are the molecular weights of the gases with...Ch. 10 - Prob. 10.70SPCh. 10 - Prob. 10.71SPCh. 10 - Hydrogen gas can be prepared by reaction of zinc...Ch. 10 - Ammonium nitrate can decompose explosively when...Ch. 10 - Prob. 10.74SPCh. 10 - Titanium(III) chloride, a substance used in...Ch. 10 - A typical high-pressure tire on a bicycle might...Ch. 10 - Prob. 10.77SPCh. 10 - Prob. 10.78SPCh. 10 - Prob. 10.79SPCh. 10 - Prob. 10.80SPCh. 10 - Prob. 10.81SPCh. 10 - A special gas mixture used in bacterial growth...Ch. 10 - A gas mixture for use in some lasers contains...Ch. 10 - Prob. 10.84SPCh. 10 - A mixture of Ar and N2 gases has a density of...Ch. 10 - A mixture of 14.2 g of H2 and 36.7 g of Ar is...Ch. 10 - A 20.0-L flask contains 0.776 g of He and 3.61 g...Ch. 10 - Prob. 10.88SPCh. 10 - Prob. 10.89SPCh. 10 - Prob. 10.90SPCh. 10 - Gaseous compound Q contains only xenon and oxygen....Ch. 10 - Prob. 10.92SPCh. 10 - Prob. 10.93SPCh. 10 - Prob. 10.94SPCh. 10 - Prob. 10.95SPCh. 10 - Prob. 10.96SPCh. 10 - Prob. 10.97SPCh. 10 - Prob. 10.98SPCh. 10 - Prob. 10.99SPCh. 10 - Prob. 10.100SPCh. 10 - Prob. 10.101SPCh. 10 - Prob. 10.102SPCh. 10 - Prob. 10.103SPCh. 10 - Prob. 10.104SPCh. 10 - Prob. 10.105SPCh. 10 - Prob. 10.106SPCh. 10 - Prob. 10.107SPCh. 10 - Prob. 10.108SPCh. 10 - Prob. 10.109SPCh. 10 - Prob. 10.110SPCh. 10 - Prob. 10.111SPCh. 10 - Prob. 10.112SPCh. 10 - Assume that you have 15.00 mol ofN2in a volume of...Ch. 10 - Uranium hexafluoride, a molecular solid used for...Ch. 10 - Use both the ideal gas law and the van der Waals...Ch. 10 - Prob. 10.116SPCh. 10 - Prob. 10.117SPCh. 10 - Prob. 10.118SPCh. 10 - Prob. 10.119SPCh. 10 - Prob. 10.120SPCh. 10 - Prob. 10.121SPCh. 10 - Prob. 10.122SPCh. 10 - Prob. 10.123SPCh. 10 - Prob. 10.124SPCh. 10 - Prob. 10.125SPCh. 10 - Prob. 10.126SPCh. 10 - Prob. 10.127SPCh. 10 - Prob. 10.128SPCh. 10 - Prob. 10.129SPCh. 10 - Prob. 10.130SPCh. 10 - Prob. 10.131SPCh. 10 - Prob. 10.132SPCh. 10 - Prob. 10.133SPCh. 10 - Prob. 10.134MPCh. 10 - Prob. 10.135MPCh. 10 - Prob. 10.136MPCh. 10 - Prob. 10.137MPCh. 10 - Prob. 10.138MPCh. 10 - Prob. 10.139MPCh. 10 - Prob. 10.140MPCh. 10 - Prob. 10.141MPCh. 10 - Prob. 10.142MPCh. 10 - Prob. 10.143MPCh. 10 - Prob. 10.144MPCh. 10 - An empty 4.00-Lsteel vesselis filled with 1.00 atm...Ch. 10 - When a gaseous compound X containing only C, H,...Ch. 10 - Isooctane, C8H18, is the component of gasoline...Ch. 10 - Prob. 10.148MPCh. 10 - Prob. 10.149MPCh. 10 - Prob. 10.150MP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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