Concept explainers
(a)
Interpretation:
Balanced chemical equation for the dissociation of
Concept-Introduction:
Electrolyte: It is a substance that is able to conduct electricity in its aqueous solution. This is due to presence of charged particles (ions) in the aqueous solution.
There are two types of electrolytes,
- Strong electrolyte: These are substances that can completely or almost completely dissociates to their corresponding ions in the aqueous solution. Strong electrolytes give solutions that are strongly conducting. Strong electrolyte includes all strong bases and strong acids and all soluble salts.
- Weak electrolyte: These are substances that dissociates incompletely into corresponding ion in aqueous solution. Weak electrolytes give solutions that are intermediate between those having strong electrolytes and those having nonelectrolytes in their ability to conduct an
electric current . Weak electrolytes include weak acids and weak bases.
Nonelectrolyte: It is a substance that does not conduct electricity in its aqueous solution. Glucose, table sugar are examples for nonelectrolytes.
(b)
Interpretation:
Balanced chemical equation for the dissociation of
Concept-Introduction:
Electrolyte: It is a substance that is able to conduct electricity in its aqueous solution. This is due to presence of charged particles (ions) in the aqueous solution.
There are two types of electrolytes,
- Strong electrolyte: These are substances that can completely or almost completely dissociates to their corresponding ions in the aqueous solution. Strong electrolytes give solutions that are strongly conducting. Strong electrolyte includes all strong bases and strong acids and all soluble salts.
- Weak electrolyte: These are substances that dissociates incompletely into corresponding ion in aqueous solution. Weak electrolytes give solutions that are intermediate between those having strong electrolytes and those having nonelectrolytes in their ability to conduct an electric current. Weak electrolytes include weak acids and weak bases.
Nonelectrolyte: It is a substance that does not conduct electricity in its aqueous solution. Glucose, table sugar are examples for nonelectrolytes.
(c)
Interpretation:
Balanced chemical equation for the dissociation of
Concept-Introduction:
Electrolyte: It is a substance that is able to conduct electricity in its aqueous solution. This is due to presence of charged particles (ions) in the aqueous solution.
There are two types of electrolytes,
- Strong electrolyte: These are substances that can completely or almost completely dissociates to their corresponding ions in the aqueous solution. Strong electrolytes give solutions that are strongly conducting. Strong electrolyte includes all strong bases and strong acids and all soluble salts.
- Weak electrolyte: These are substances that dissociates incompletely into corresponding ion in aqueous solution. Weak electrolytes give solutions that are intermediate between those having strong electrolytes and those having nonelectrolytes in their ability to conduct an electric current. Weak electrolytes include weak acids and weak bases.
Nonelectrolyte: It is a substance that does not conduct electricity in its aqueous solution. Glucose, table sugar are examples for nonelectrolytes.
(d)
Interpretation:
Balanced chemical equation for the dissociation of
Concept-Introduction:
Electrolyte: It is a substance that is able to conduct electricity in its aqueous solution. This is due to presence of charged particles (ions) in the aqueous solution.
There are two types of electrolytes,
- Strong electrolyte: These are substances that can completely or almost completely dissociates to their corresponding ions in the aqueous solution. Strong electrolytes give solutions that are strongly conducting. Strong electrolyte includes all strong bases and strong acids and all soluble salts.
- Weak electrolyte: These are substances that dissociates incompletely into corresponding ion in aqueous solution. Weak electrolytes give solutions that are intermediate between those having strong electrolytes and those having nonelectrolytes in their ability to conduct an electric current. Weak electrolytes include weak acids and weak bases.
Nonelectrolyte: It is a substance that does not conduct electricity in its aqueous solution. Glucose, table sugar are examples for nonelectrolytes.
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GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
- A solution is prepared from 0.150 mol of formic acid and enough water to make 0.425 L of solution. a Determine the concentrations of H3O+ and HCOO in this solution. b Determine the H3O+ concentration that would be necessary to decrease the HCOO concentration above by a factor of 10. How many milliliters of 2.00 M HCl would be required to produce this solution? Consider that the solution was made by combining the HCl, the HCOOH, and enough water to make 0.425 L of solution. c Qualitatively, how can you account for the differences in the percentage dissociation of formic acid in parts a and b of this problem?arrow_forwardWrite a balanced chemical equation for the dissociation in water of each of the salts listed in Problem 10-131. a. NaCl b. Mg(NO3)2 c. K2S d. NH4CNarrow_forwardHydrazine, N2H4, can interact with water in two steps. N2H4(aq) + H2O() N2H5+(aq) + OH(aq) Kb1 = 8.5 107 N2H5+(aq) + H2O() N2H62+(aq) + OH(aq) Kb2 = 8.9 1016 (a) What is the concentration of OH, N2H5+ and N2H62+ in a 0.010M aqueous solution of hydrazine? (b) What is the pH of the 0.010M solution hydrazine?arrow_forward
- . The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.arrow_forwardStrong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.arrow_forwardTwo strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forward
- What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?arrow_forwardCalculate the concentration of all solute species in each of the following solutions of acids or bases. Assume that the ionization of water can be neglected, and show that the change in the initial concentrations can be neglected, Ionization constants can be found in Appendix H and Appendix I. (a) 0.0092 M HCIO, a weak acid. (b) 0.0784 M C6H5NH2, a weak base. (c) 0.0810 M HCN, a weak acid. (d) 0.11 M (CH3)3N, a weak base. (e) 0.120 M Fe(H2O)62+ a weak acid, Ka=1.6107arrow_forwardEach of the following statements concerns a 0.10 M solution of a weak organic base, B. Briefly describe why each statement is either true or false. a [B] is approximately equal to 0.10 M. b [B] is much greater than [HB+]. c [H3O+] is greater than [HB+]. d The pH is 13. e [HB+] is approximately equal to [OH]. f [OH] equals 0.10 M.arrow_forward
- Classify each of the following compounds as a strong electrolyte or a weak electrolyte. a. H3PO4 b. HNO3 c. KNO3 d. NaOHarrow_forwardWrite chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2CO3 (carbonic acid) b. H2C3H2O4 (malonic acid)arrow_forwardWhen all the water is evaporated from a sodium hydroxide solution, solid sodium hydroxide is obtained. However, if you evaporate the water in an ammonium hydroxide solution, you will not produce solid ammonium hydroxide. Explain why. What will remain after the Water is evaporated?arrow_forward
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