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Concept explainers
(a)
Interpretation:
Lewis structures of all the important resonance forms of
Concept introduction:
Steps to draw the Lewis structure of the molecule are as follows:
Step 1: Find the central atom and place the other atoms around it. The atom in a compound which has the lowest group number or lowest electronegativity considered as the central atom.
Step 2: Calculate the total number of valence electrons.
Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond.
Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons.
When bonds in a molecule can be expressed by different Lewis structures then resonance structures are used to depict the bonding in that molecule. These resonance structures have the same placement of atoms but different locations of bonding and lone pairs of electrons also one resonance form can be converted intoanother by moving lone pairs to bonding positions, and vice versa.
(b)
Interpretation:
Lewis structures of all the important resonance forms of
Concept introduction:
Steps to draw the Lewis structure of the molecule are as follows:
Step 1: Find the central atom and place the other atoms around it. The atom in a compound which has the lowest group number or lowest electronegativity considered as the central atom.
Step 2: Calculate the total number of valence electrons.
Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond.
Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons.
When bonds in a molecule can be expressed by different Lewis structures then resonance structures are used to depict the bonding in that molecule. These resonance structures have the same placement of atoms but different locations of bonding and lone pairs of electrons also one resonance form can be converted intoanother by moving lone pairs to bonding positions, and vice versa.
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Chapter 10 Solutions
Student Study Guide for Silberberg Chemistry: The Molecular Nature of Matter and Change
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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