Chemistry: A Molecular Approach Plus Mastering Chemistry with Pearson eText -- Access Card Package (4th Edition) (New Chemistry Titles from Niva Tro)
4th Edition
ISBN: 9780134103976
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 79E
Interpretation Introduction
Interpretation: The given numbers are to be identified whether they are exact or not..
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and
dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a
resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if
applicable).
ード
M
4-
b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible
isomers and their corresponding point groups. Use the point groups to determine if the complexes have
resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if
applicable). The number of complex sketches below is not necessarily indicative of the number of isomers.
4-
4-
☐☐☐
c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible
isomers and their corresponding point groups.. Use the point groups to determine if the complexes have
resulting net dipole…
Show work. don't give Ai generated solution
Chapter 1 Solutions
Chemistry: A Molecular Approach Plus Mastering Chemistry with Pearson eText -- Access Card Package (4th Edition) (New Chemistry Titles from Niva Tro)
Ch. 1 - A chemist mixes sodium with water and witnesses a...Ch. 1 - Q2. This image represents a particulate view of a...Ch. 1 - Which change is a physical change? a) Wood burning...Ch. 1 - Q4. Which property of rubbing alcohol is a...Ch. 1 - Convert 85F to K. a) 181.1 K b) 358 K c) 29.4 K d)...Ch. 1 - Express the quantity 33.2 10?4 m in mm. a) 33.2...Ch. 1 - Q7. What is the mass of a 1.75 L sample of a...Ch. 1 - Perform the calculation to the correct number of...Ch. 1 - Q9. Perform the calculation to the correct number...Ch. 1 - Q10. Convert 1285 cm2 to m2.
a) 1.285 × 107...
Ch. 1 - Q11. The first diagram depicts a compound in its...Ch. 1 - Q12. Three samples, each of a different substance,...Ch. 1 - Q13. A solid metal sphere has a radius of 3.53 cm...Ch. 1 - Q14. The gas mileage of a certain German...Ch. 1 - Q15. A wooden block has a volume of 18.5 in3....Ch. 1 - 1. Explain this statement in your own words and...Ch. 1 - Prob. 2ECh. 1 - 3. Describe the scientific approach to knowledge....Ch. 1 - 4. Explain the differences between a hypothesis, a...Ch. 1 - 5. What observations did Antoine Lavoisier make?...Ch. 1 - 6. What theory did John Dalton formulate?
Ch. 1 - 7. What is wrong with the expression “That is just...Ch. 1 - 8. What are two different ways to classify...Ch. 1 - 9. How do solids, liquids, and gases differ?
Ch. 1 - 10. What is the difference between a crystalline...Ch. 1 - 11. Explain the difference between a pure...Ch. 1 - 12. Explain the difference between an element and...Ch. 1 - 13. Explain the difference between a homogeneous...Ch. 1 - 14. What kind of mixtures can be separated by...Ch. 1 - 15. Explain how distillation is used to separate...Ch. 1 - 16. What is the difference between a physical...Ch. 1 - 17. What is the difference between a physical...Ch. 1 - 18. Explain the significance of the law of...Ch. 1 - Prob. 19ECh. 1 - 20. What are the standard SI base units of length,...Ch. 1 - 21. What are the three common temperature scales?...Ch. 1 - 22. What are prefix multipliers? List some...Ch. 1 - 23. What is a derived unit? List an example.
Ch. 1 - 24. Explain the difference between density and...Ch. 1 - 25. Explain the difference between intensive and...Ch. 1 - 26. What is the meaning of the number of digits...Ch. 1 - 27. When multiplying or dividing measured...Ch. 1 - 28. When adding and subtracting measured...Ch. 1 - 29. What are the rules for rounding off the...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - 32. What is dimensional analysis?
Ch. 1 - 33. Classify each statement as an observation, a...Ch. 1 - 34. Classify each statement as an observation, a...Ch. 1 - 35. A chemist decomposes several samples of carbon...Ch. 1 - 36. When astronomers observe distant galaxies,...Ch. 1 - 37. Classify each substance as a pure substance or...Ch. 1 - 38. Classify each substance as a pure substance or...Ch. 1 - 39. Complete the table.
Substance Pure or...Ch. 1 - 40. Complete the table.
Substance Pure or...Ch. 1 - 41. Determine whether each molecular diagram...Ch. 1 - 42. Determine whether each molecular diagram...Ch. 1 - 43. Classify each of the listed properties of...Ch. 1 - Prob. 44ECh. 1 - Prob. 45ECh. 1 - 46. Classify each property as physical or...Ch. 1 - 47. Classify each change as physical or...Ch. 1 - Prob. 48ECh. 1 - 49. Based on the molecular diagram, classify each...Ch. 1 - 50. Based on the molecular diagram, classify each...Ch. 1 - 51. Convert each temperature.
a. F to ...Ch. 1 - 52. Convert each temperature.
a. F to ...Ch. 1 - 53. The coldest temperature ever measured in the...Ch. 1 - Prob. 54ECh. 1 - 55. Use the prefix multiplier to express each...Ch. 1 - 56. Use the prefix multiplier to express each...Ch. 1 - 57. Use scientific notation to express each...Ch. 1 - 58. Use scientific notation to express each...Ch. 1 - 59. Complete the table.
a. 1245 kg 1.245 × 106...Ch. 1 - 60. Complete the table.
a. 355...Ch. 1 - 61. Express the quantity 254,998 m in each...Ch. 1 - 62. Express the quantity in each unit.
a. ms
b....Ch. 1 - 63. How many 1 cm squares would it take to...Ch. 1 - Prob. 64ECh. 1 - 65. A new penny has a mass of 2.49 g and a volume...Ch. 1 - 66. A titanium bicycle frame displaces 0.314 L of...Ch. 1 - 67. Glycerol is a syrupy liquid often used in...Ch. 1 - 68. A supposedly gold nugget displaces 19.3 mL of...Ch. 1 - 69. Ethylene glycol (antifreeze) has a density of...Ch. 1 - 70. Acetone (nail polish remover) has a density of...Ch. 1 - 71. A small airplane takes on 245 L of fuel. If...Ch. 1 - 72. Human fat has a density of . How much volume ...Ch. 1 - Prob. 73ECh. 1 - 74. Read each measurement to the correct number of...Ch. 1 - 75. For each number, underline the zeros that are...Ch. 1 - 76. For each number, underline the zeros that are...Ch. 1 - 77. How many significant figures are in each...Ch. 1 - 78. How many significant figures are in each...Ch. 1 - Prob. 79ECh. 1 - 80. Indicate the number of significant figures in...Ch. 1 - 81. Round each number to four significant...Ch. 1 - Prob. 82ECh. 1 - 83. Calculate to the correct number of significant...Ch. 1 - 84. Calculate to the correct number of significant...Ch. 1 - 85. Calculate to the correct number of significant...Ch. 1 - 86. Calculate to the correct number of significant...Ch. 1 - 87. Calculate to the correct number of significant...Ch. 1 - 88. Calculate to the correct number of significant...Ch. 1 - Prob. 89ECh. 1 - 90. A flask containing 9.55 mL of a liquid weighs...Ch. 1 - Prob. 91ECh. 1 - 92. Perform each unit conversion.
a. 28.9 nm to...Ch. 1 - Prob. 93ECh. 1 - Prob. 94ECh. 1 - 95. A runner wants to run 10.0 km. Her running...Ch. 1 - 96. A cyclist rides at an average speed of 18 mi...Ch. 1 - 97. A certain European automobile has a gas...Ch. 1 - 98. A gas can holds 5.0 gal of gasoline. Express...Ch. 1 - 99. A house has an area of . What is its area in...Ch. 1 - Prob. 100ECh. 1 - 101. The average U.S. farm occupies 435 acres. How...Ch. 1 - Prob. 102ECh. 1 - 103. An acetaminophen suspension for infants...Ch. 1 - Prob. 104ECh. 1 - Prob. 105ECh. 1 - 106. Determine the number of picoseconds in 2.0...Ch. 1 - 107. Classify each property as intensive or...Ch. 1 - 108. At what temperature are the readings on the...Ch. 1 - 109. Suppose you design a new thermometer called...Ch. 1 - 110. On a new Jekyll temperature scale, water...Ch. 1 - 111. Force is defined as mass times acceleration....Ch. 1 - Prob. 112ECh. 1 - 113. Do each calculation without your calculator...Ch. 1 - Prob. 114ECh. 1 - 115. A thief uses a can of sand to replace a solid...Ch. 1 - 116. The proton has a radius of approximately and...Ch. 1 - 117. The density of titanium is . What is the...Ch. 1 - 118. The density of iron is . What is its density...Ch. 1 - Prob. 119ECh. 1 - 120. A solid aluminum sphere has a mass of 85 g....Ch. 1 - 121. A backyard swimming pool holds 185 cubic...Ch. 1 - 122. An iceberg has a volume of . What is the mass...Ch. 1 - 123. The Toyota Prius, a hybrid electric vehicle,...Ch. 1 - Prob. 124ECh. 1 - Prob. 125ECh. 1 - 126. A sample of gaseous neon atoms at atmospheric...Ch. 1 - Prob. 127ECh. 1 - Prob. 128ECh. 1 - 129. Table salt contains 39.33 g of sodium per 100...Ch. 1 - Prob. 130ECh. 1 - 131. A length of 8 copper wire (radius = 1.63 mm)...Ch. 1 - 132. Rolls of aluminum foil are 304 mm wide and...Ch. 1 - Prob. 133ECh. 1 - 134. Mercury is often used in thermometers. The...Ch. 1 - 135. A force of is applied to a diver’s face mask...Ch. 1 - Prob. 136ECh. 1 - Prob. 137ECh. 1 - Prob. 138ECh. 1 - Prob. 139ECh. 1 - 140. Nanotechnology, the field of building...Ch. 1 - Prob. 141ECh. 1 - 142. A box contains a mixture of small copper...Ch. 1 - 143. A volatile liquid (one that easily...Ch. 1 - Prob. 144ECh. 1 - Prob. 145ECh. 1 - Prob. 146ECh. 1 - Prob. 147ECh. 1 - 148. Let a triangle represent atoms of element A...Ch. 1 - 149. Identify each statement as being most like an...Ch. 1 - Prob. 150QGWCh. 1 - 151. Look up the measurement of the approximate...Ch. 1 - Prob. 152QGWCh. 1 - Prob. 153QGWCh. 1 - Prob. 154QGWCh. 1 - 155. The graph in Figure a▼ plots the density of...
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