To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2. Concept introduction: Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known. To identify: To identify whether the two given compounds possess any formal charge.

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Answer 1

Question

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

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Questions 4 and 5

For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.

Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.

Answer 2

Question

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

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Answer 3

Question

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

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Answer 4

Question

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

Expert Solution & Answer

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Answer 5

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

Answer 6

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

Answer 7

Chapter 1, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

To identify: To identify whether the two given compounds possess any formal charge.

Answer 8

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

Formal charge on a atom is the charge that is associated with the atom that does not have appropriate number of valence electrons. To find the formal charge on an atom in a compound the total number of valence electrons of the atom must be known.

Answer 10

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

Answer 11

(c)

Interpretation Introduction

Interpretation:

To identify the formal charges that are missing from structure 1 and 2. To determine which of the two compound will be more soluble in polar solvent. To determine the amount of increase in bond angle C-C-N when 1 is converted to 2.

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound. This mixing of hybrid orbitals is known as hybridization. The hybridization determines the geometry of the particular atom in the compound. Shortly to say

sp3hybridized =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

sp2hybridized =trigonal planar

sp hybridized =linear

Each and every hybridized orbital has its own bond angle,

sp3hybridized = 109.5°

sp2hybridized = 120°

sp hybridized = 180°

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 1.2 - Draw all constitutional isomers that have the...Ch. 1.2 - Prob. 1PTS Ch. 1.2 - APPLY the skill Chlorofluorocarbons (CFCs) are...Ch. 1.3 - Prob. 2LTS Ch. 1.3 - Prob. 3PTS Ch. 1.3 - Prob. 4PTS Ch. 1.3 - Prob. 5PTS Ch. 1.3 - Prob. 6PTS Ch. 1.3 - Lithium salts have been used for decades to treat...Ch. 1.3 - Prob. 3LTS

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