EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 1, Problem 64P
a. Which of the indicated bonds in each molecule is shorter?
b. Indicate the hybridization of the C, O, and N atoms in each of the molecules.
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List the correct electron and molecular geometries that correspond to each set of electron groups around the central atom of a molecule.a. four electron groups overall; three bonding groups and onelone pairb. four electron groups overall; two bonding groups and two lone pairsc. five electron groups overall; four bonding groups and one lone paird. five electron groups overall; three bonding groups and two lone pairse. five electron groups overall; two bonding groups and three lone pairsf. six electron groups overall; five bonding groups and one lone pairg. six electron groups overall; four bonding groups and two lone pairs
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Chapter 1 Solutions
EBK ORGANIC CHEMISTRY
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 7.59 What type of hybrid orbital is generated by combining the valence s orbital and all three valence p orbitals of an atom? How many hybrid orbitals result?arrow_forwardLets look more closely at the process of hybridization. (a) What is the relationship between the number of hybrid orbitals produced and the number of atomic orbitals used to create them? (b) Do hybrid atomic orbitals form between different p orbitals without involving 5 orbitals? (c) What is the relationship between the energy of hybrid atomic orbitals and the atomic orbitals from which they are formed?arrow_forwardWhat hybrid orbitals would be expected for the central atom in each of the following molecules or ions?arrow_forward
- The antibiotic thiarubin-A was discovered by studying the feeding habits of wild chimpanzees in Tanzania. The structure for thiarubin-A is a. Complete the Lewis structure, showing all lone pairs of electrons. b. Indicate the hybrid orbitals used by the carbon and sulfur atoms in thiarubin-A. c. How many and bonds are present in this molecule?arrow_forward• explain how hybridization reconciles observed molecular shapes with the orbital overlap model.arrow_forwardMethylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) How many sigma bonds are in the molecule? (b) How many pi bonds are in the molecule? (c) What is the hybridization of the carbon atom bonded to nitrogen? (d) What is the hybridization of the carbon atom bonded to oxygen? (e) What is the hybridization of the double-bonded oxygen?arrow_forward
- 7.96 Consider the hydrocarbons whose structures are shown below. Which of these molecules would be planar, meaning that all of the atoms must lie in the same plane? Explain your answer in terms of orbital hybridizations.arrow_forwardDescribe the shapes of C2H6 and C2H4. In doing so, explain why one molecule is planar and why the other molecule cannot be planar.arrow_forwardIndigo is the dye used in coloring blue jeans. The term navy blue is derived from the use of indigo to dye British naval uniforms in the eighteenth century. The structure of the indigo molecule is a. How many bonds and bonds exist in the molecule? b. What hybrid orbitals are used by the carbon atoms in the indigo molecule?arrow_forward
- Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na,2+ (b) Mg,2 (c) AI,2 (d) Si,2 (e) p2+ (f) s,2 (g) F,2 (h) Ar,2 40. Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na22+ (b) Mg22+ (c) Al22+ (d) Si22+ (e) P22+ (f) S22+ (g) F22+ (h) Ar22+arrow_forwardIdentify the hybrid orbitals used by boron in BCl3 and in BCl4, the ion formed from the reaction of BCl3 and Cl. Explain your choices.arrow_forward• explain the formation of multiple bonds in terms of the overlap of a combination of hybridized and unhybridized atomic orbitals.arrow_forward
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