EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 9780100552234
Author: ZUMDAHL
Publisher: YUZU
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Chapter 1, Problem 60CWP
Interpretation Introduction
Interpretation: Number of proton and neutron are given for the isotope. By using these numbers, the symbols of the isotopes are to be determined and filled in the table.
Concept introduction: In a neutral atom, the number of protons and electrons are same and equal to the
To determine: The symbols of the isotopes in the table.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 1 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 1 - Define and e xplain the differences between the...Ch. 1 - Is the scientific method suitable for solving...Ch. 1 - Use Daltons atomic theory to account for each of...Ch. 1 - What evidence led to the conclusion that cathode...Ch. 1 - What discoveries were made by J. J. Thomson, Henri...Ch. 1 - Consider Ernest Rutherfords -particle bombardment...Ch. 1 - Do the proton and the neutron have exactly the...Ch. 1 - What is the distinction between atomic number and...Ch. 1 - Paracelsus, a sixteenth-century alchemist and...Ch. 1 - What is wrong with the following statement? The...
Ch. 1 - Which of the following is true about an individual...Ch. 1 - These questions concern the work of J. J. Thomson....Ch. 1 - Which of the following explain how an ion is...Ch. 1 - You have a chemical in a sealed glass container...Ch. 1 - You may have noticed that when water boils, you...Ch. 1 - One of the best indications of a useful theory is...Ch. 1 - Prob. 9ALQCh. 1 - Which (if any) of the following can be determined...Ch. 1 - The difference between a law and a theory is the...Ch. 1 - As part of a science project, you study traffic...Ch. 1 - Explain the fundamental steps of the scientific...Ch. 1 - When hydrogen is burned in oxygen to form water,...Ch. 1 - Explain the law of conservation of mass, the law...Ch. 1 - Chlorine has two natural isotopes: C1737I and...Ch. 1 - The vitamin niacin (nicotinic acid, C6H5NO2) can...Ch. 1 - Section 1-5 describes the postulates of Daltons...Ch. 1 - The contributions of J. J. Thomson and Ernest...Ch. 1 - What is the modern view of the structure of the...Ch. 1 - The number of protons in an atom determines the...Ch. 1 - If the volume of a proton is similar to the volume...Ch. 1 - Prob. 23QCh. 1 - What refinements had to be made in Daltons atomic...Ch. 1 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 1 - Observations of the reaction between nitrogen gas...Ch. 1 - A sample of chloroform is found to contain 12.0 g...Ch. 1 - A sample of H2SO4 contains 2.02 g of hydrogen,...Ch. 1 - Hydrazine, ammonia, and hydrogen azide al1 contain...Ch. 1 - Consider 100.0-g samples of two different...Ch. 1 - The three most stable oxides of carbon are carbon...Ch. 1 - Two elements, R and Q, combine to form two binary...Ch. 1 - Prob. 33ECh. 1 - In a combustion reaction, 46.0 g of ethanol reacts...Ch. 1 - Early tables of atomic weights (masses) were...Ch. 1 - Indium oxide contains 4.784 g of indium for every...Ch. 1 - Prob. 37ECh. 1 - If you wanted to make an accurate scale model of...Ch. 1 - In an experiment it was found that the total...Ch. 1 - A chemist in a galaxy far, far away performed the...Ch. 1 - Write the symbol of each atom using the ZAX...Ch. 1 - For carbon-14 and carbon-12, how many protons and...Ch. 1 - How many protons and neutrons are in the nucleus...Ch. 1 - What number of protons and neutrons is contained...Ch. 1 - Prob. 45ECh. 1 - Write the atomic symbol (ZAX) for each of the...Ch. 1 - For each of the following ions, indicate the...Ch. 1 - How many protons, neutrons, and electrons are in...Ch. 1 - Prob. 49ECh. 1 - What is the symbol of an ion with 16 protons, 18...Ch. 1 - Complete the following table:Ch. 1 - Complete the following table:Ch. 1 - Four Fe2+ ions are key components of hemoglobin,...Ch. 1 - Which of the following statements is/are true? For...Ch. 1 - Identify each of the following elements. Give the...Ch. 1 - The isotope of an unknown element, X, has a mass...Ch. 1 - Prob. 57AECh. 1 - The early alchemists used to do an experiment in...Ch. 1 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 1 - Prob. 60CWPCh. 1 - Complete the following table. Atmos Number of...Ch. 1 - Complete the following table.Ch. 1 - Which of the following is( are) correct? a. C40a2+...Ch. 1 - Prob. 64CPCh. 1 - Each of the following statements is true, but...Ch. 1 - Reaction of 2.0 L of hydrogen gas with 1.0 L of...Ch. 1 - A combustion reaction involves the reaction of a...Ch. 1 - A chemistry instructor makes the following claim:...Ch. 1 - You have two distinct gaseous compounds made from...Ch. 1 - Using the information in Table 1-1, answer the...Ch. 1 - A single molecule has a mass of 7.31 1023 g....Ch. 1 - You have gone back in time and are working with...
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