Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 1, Problem 5P
A sample of ascorbic acid (vitamin C) is synthesized in the laboratory. It contains 30.0 g carbon and 40.0 g oxygen. Another sample of ascorbic acid, isolated from lemons (an excellent source of the vitamin), contains 12.7 g carbon. Compute the mass of oxygen (in grams) in the second sample.
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
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Q7
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Grignard 1
OH
H3O+
Grignard 2
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MgBr
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CH3CH2CH2MgBr
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2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
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Chapter 1 Solutions
Principles of Modern Chemistry
Ch. 1 - Classify the following materials as substances or...Ch. 1 - Classify the following materials as substances or...Ch. 1 - A 17th-century chemist wrote of the “simple bodies...Ch. 1 - Since 1800, almost 200 sincere but erroneous...Ch. 1 - A sample of ascorbic acid (vitamin C) is...Ch. 1 - A sample of a compound synthesized and purified in...Ch. 1 - Nitrogen (N) and silicon (Si) form two binary...Ch. 1 - Iodine (I) and fluorine (F) form a series of...Ch. 1 - Vanadium (V) and oxygen (O) form a series of...Ch. 1 - Prob. 10P
Ch. 1 - Prob. 11PCh. 1 - Prob. 12PCh. 1 - Pure nitrogen dioxide (NO2) forms when dinitrogen...Ch. 1 - Gaseous methanol (CH3OH) reacts with oxygen (O2)...Ch. 1 - In J. J. Thompson’s experiment depicted in Figures...Ch. 1 - In the problem 15 above, what is vy , the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - Prob. 19PCh. 1 - More than half of all the atoms in naturally...Ch. 1 - The isotope of plutonium used for nuclear fission...Ch. 1 - The last “missing” element from the first six...Ch. 1 - Prob. 23PCh. 1 - In 1982, the production of a single atom of...Ch. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Compute the relative molecular masses of the...Ch. 1 - Prob. 28PCh. 1 - Suppose that a person counts out gold atoms at the...Ch. 1 - A gold atom has a diameter of 2.881010m . Suppose...Ch. 1 - The vitamin A molecule has the formula C20H30O ,...Ch. 1 - Arrange the following in order of increasing mass:...Ch. 1 - Mercury is traded by the “flask,” a unit that has...Ch. 1 - Gold costs $400 per troy ounce, and...Ch. 1 - Aluminum oxide (Al2O3) occurs in nature as a...Ch. 1 - Prob. 36PCh. 1 - Soft wood chips weighing 17.2 kg are placed in an...Ch. 1 - In a reproduction of the Millikan oil-drop...Ch. 1 - A rough estimate of the radius of a nucleus is...Ch. 1 - In a neutron star, gravity causes the electrons to...Ch. 1 - Prob. 41APCh. 1 - Naturally occurring rubidium (Rb) consists of two...Ch. 1 - A sample of a gaseous binary compound of boron and...
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- 2) (4 pt) After the reaction was completed, the student collected the following data. Crude product data is the data collected after the reaction is finished, but before the product is purified. "Pure" product data is the data collected after attempted purification using recrystallization. Student B's data: Crude product data "Pure" product data after recrystallization Crude mass: 0.93 g grey solid Crude mp: 96-106 °C Crude % yield: Pure mass: 0.39 g white solid Pure mp: 111-113 °C Pure % yield: a) Calculate the crude and pure percent yields for the student's reaction. b) Summarize what is indicated by the crude and pure melting points.arrow_forwardDon't used hand raitingarrow_forwardDon't used hand raitingarrow_forward
- Don't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forwardDon't used hand raitingarrow_forward
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