EBK FOUNDATIONS OF COLLEGE CHEMISTRY
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 1, Problem 4RQ

(a)

Interpretation Introduction

Interpretation:

The description “It has a regular pattern” refers to a crystalline solid or amorphous solid has to be given.

Concept Introduction:

Crystalline solid:

The solids in which the constituent particles of matter are arranged and organized in a specific manner are called crystalline solid.  These solids contain crystals in their structure and each crystal has definite geometry.  Almost all solids fall in the category of crystalline solids including metallic elements iron, silver and copper and non-metallic elements phosphorous, sulphur and iodine.

Amorphous solid:

The solids in which the constituent particles of matter are arranged in a random manner are called amorphous solids.  It is a non-crystalline solid with no proper arrangement of atoms in the solid lattice.  The most common examples of amorphous solids are glass.

(b)

Interpretation Introduction

Interpretation:

Plastic refers to a crystalline solid or amorphous solid has to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The description “It has a no regular pattern” refers to a crystalline solid or amorphous solid has to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Glass refers to a crystalline solid or amorphous solid has to be given

Concept Introduction:

Refer to part (a).

(e)

Interpretation Introduction

Interpretation:

Gold refers to a crystalline solid or amorphous solid has to be given

Concept introduction:

Refer to part (a).

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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