The condensed formula should be converted to hashed and wedged form. Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds. Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Answer 1

Question

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

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1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?

Explain Huckel's rule.

Answer 2

Question

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

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Answer 3

Question

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

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Answer 4

Question

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

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Answer 5

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 6

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 7

Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 8

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 9

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 10

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 11

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 12

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 13

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

Answer 14

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Answer 17

Ch. 1.3 - Prob. 1.1E Ch. 1.3 - Prob. 1.2E Ch. 1.3 - Prob. 1.3E Ch. 1.3 - Prob. 1.4E Ch. 1.3 - Prob. 1.5E Ch. 1.4 - Prob. 1.6E Ch. 1.4 - Prob. 1.8TIY Ch. 1.5 - Prob. 1.9E Ch. 1.5 - Prob. 1.11TIY Ch. 1.6 - Prob. 1.12E

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