Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
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Chapter 1, Problem 42E

Perform the following mathematical operations, and express the result to the correct number of significant figures.

  1. a. 6.022 X 10-23 × 1.05 x 102
  2. b. 6.6262 × 10 34 × 2.998 × 10 8 2.54 × 10 9
  3. c. 1.285 × 10−2 + 1.24 × 10−3 + 1.879 × 10−1
  4. d. ( 1.00866  - 1 .00728 ) 6.02205   ×  10 23
  5. e. 9.875 × 10 2 9.795 × 10 2 9.875 × 10 2 × 100   ( 100  is exact )
  6. f. 9.42 × 10 2 + 8.234 × 10 2 + 1.625 × 10 3 3 ( 3  is exact )

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 6.32×1025.

Explanation of Solution

Given data:

6.022×1023×1.05×102

Take the multiplication of the given values

6.022×1023×1.05×102=6.022×1.05×1025=6.3231×1025

The answer is 6.32×1025.

The result is 6.3231×1025.  Here the limiting term 1.05 has two decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 7.82×10-17.

Explanation of Solution

Given data:

6.6262×10-34×2.998×1082.54×10-9

First, take the multiplication of the given values

6.6262×10-34×2.998×108=6.6262×2.998×10-26=19.8653×10-26

Now, take the division of the obtained values

19.8653×10-262.54×10-9=7.821×10-26+9=7.821×10-17

The answer is 7.82×10-17.

The result is 7.821×10-17.  Here the limiting term 2.54 has two decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 0.20.

Explanation of Solution

Given data:

1.285×10-2+1.24×10-3+1.879×10-1

First, convert the given numbers into same scientific notation

1.285×10-2=1.285×10-21.24×10-3=0.124×10-21.879×10-1=18.79×10-2

Now, take the addition of the obtained values

(1.285+0.124+18.79)×102=(20.199)×102=0.20199

The answer is 0.20.

The result is 0.20199.  Here the limiting term 1.24 has two decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

(d)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 2.29158×10-27.

Explanation of Solution

Given data:

(1.00866-1.00728)6.02205×1023

First, take subtraction of the given values

1.00866-1.00728=0.00138

Now, take the division of the obtained values

0.001386.02205×1023=0.0002291578×10-23=2.29158×10-27

The answer is 2.29158×10-27.

The result is 2.291578×10-27.  Here the limiting term 1.00866 has five decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

(e)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 81.013.

Explanation of Solution

Given data:

9.875×102-9.795×1029.875×102×100

First, take subtraction of the given values

9.875×102-9.795×102=8×102

Now, take the division of the obtained values

8×1029.87×102×100=0.810×100=81.01266

The answer is 81.013.

The result is 81.01266.  Here the limiting terms 9.875 has three decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

(f)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

For the given set of mathematical calculations the answer has to be given in appropriate number of significant figures.

Concept introduction:

Significant figures: The digits having a meaning in a given number are called as significant figures.

Significant figures – calculation rules

  • Significant figure is a non-zero number (4443.2 has five significant figures)
  • Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
  • Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
  • Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
  • Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures).  In this cases use scientific notation to avoid ambiguity.
  • The placement of decimal at the trailing zero is indicates the zero is significant (550. has three significant figures).

Answer to Problem 42E

The answer is 11.30×102.

Explanation of Solution

Given data:

9.42×102+8.234×102+1.625×1033

First, convert the given numbers into same scientific notation

9.42×102=9.42×1028.234×102=8.234×1021.625×103=16.25×102

Then, take the addition of the obtained values

(9.42+8.234+16.25)×102=33.904×102

Now take the division of the obtained values

33.9043×102=11.3013×102

The answer is 11.30×102.

The result is 11.3013×102.  Here the limiting terms 9.42 has two decimal places.  Hence, the obtained result was rounded off to get the final result with appropriate number of significant figures.

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Chapter 1 Solutions

Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition

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