Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 1, Problem 28E
Classify each of the following properties as chemical or physical:
a. the tendency of silver to tarnish
b. the flammability of alcohol
c. the volatility (ease of vaporization) of alcohol
d. the malleability (ability to be pounded into sheets) of metal
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 1 Solutions
Chemistry In Focus
Ch. 1 - A chemist observes the behavior of a gas by...Ch. 1 - Classifying Matter Determine whether each of the...Ch. 1 - A cup of coffee is an example of: a. a liquid pure...Ch. 1 - Water is put on the stove and heated with a...Ch. 1 - The Conservation of Mass A match is weighed and...Ch. 1 - Constant Composition of Compounds Two samples of...Ch. 1 - Prob. 4SCCh. 1 - What is meant by the statement Macroscopic...Ch. 1 - Why should nonscience majors study science?Ch. 1 - Prob. 3E
Ch. 1 - Define chemistry.Ch. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - How are science and art similar? How are they...Ch. 1 - What is different about the Greek philosophers...Ch. 1 - Match each of the people in column A with their...Ch. 1 - What were the two main pursuits of alchemy? What...Ch. 1 - Prob. 11ECh. 1 - What is the difference between an element and a...Ch. 1 - What is the difference between a pure substance...Ch. 1 - What is the difference between a homogeneous...Ch. 1 - Explain the differences among a solid, a liquid,...Ch. 1 - Match each term in the left column with three...Ch. 1 - What is the atomic theory?Ch. 1 - Describe Rutherfords gold foil experiment.Ch. 1 - Describe the structure of the atom as explained by...Ch. 1 - What are black holes, and how does their existence...Ch. 1 - Classify each of the following as an observation...Ch. 1 - Classify each of the following as a law or a...Ch. 1 - To the best of your knowledge, classify each of...Ch. 1 - To the best of your knowledge, classify each of...Ch. 1 - Which substance is a liquid mixture? a. lemonade...Ch. 1 - Which substance is a solid? a. the helium in a...Ch. 1 - Classify each of the following properties as...Ch. 1 - Classify each of the following properties as...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - The burning of gasoline in automobile engines is a...Ch. 1 - A campfire is a chemical reaction involving wood...Ch. 1 - Prob. 33ECh. 1 - Prob. 34ECh. 1 - A chemist combines 22 grams of sodium with 28...Ch. 1 - A chemist combines 6 grams of hydrogen with 52...Ch. 1 - Several samples of carbon dioxide are obtained and...Ch. 1 - Several samples of methane gas, the primary...Ch. 1 - According to Rutherfords model of the atom, how...Ch. 1 - According to Rutherfords model of the atom, how...Ch. 1 - When water boils, small bubbles form in the...Ch. 1 - Prob. 42ECh. 1 - Prob. 43ECh. 1 - Prob. 44ECh. 1 - Prob. 45ECh. 1 - The nuclei of a limited number of atoms are...Ch. 1 - Prob. 47ECh. 1 - Based on the molecular views shown for each of the...Ch. 1 - Read The Molecular Revolution" box in this chapter...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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