
General Chemistry: Principles and Modern Applications, Loose Leaf Version (11th Edition)
11th Edition
ISBN: 9780133897319
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Question
Chapter 1, Problem 26E
Interpretation Introduction
Interpretation:
Using the concept of significant figures, the way in which the given information was presented should be criticized.
Concept introduction:
Any measurement involves estimation and thus is uncertain to some extent. The degree of certainty for a measurement is signified by the number of significant figures.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 1 Solutions
General Chemistry: Principles and Modern Applications, Loose Leaf Version (11th Edition)
Ch. 1 - What are the principal reasons that one theory...Ch. 1 - Prob. 2ECh. 1 - A common belief among scientists is that there...Ch. 1 - Describe several ways in which a scientific law...Ch. 1 - Describe the necessary characteristics of an...Ch. 1 - Describe the necessary characteristics of a...Ch. 1 - State whether the following properties of matter...Ch. 1 - State whether the following properties are...Ch. 1 - Indicate whether each sample of matter listed is 8...Ch. 1 - Indicate whether each sample of matter listed is...
Ch. 1 - Suggest physical changes by which the following...Ch. 1 - What type of changephysical or chemicalis...Ch. 1 - Express each number in exponential notation....Ch. 1 - Express each number common decimal form. a....Ch. 1 - Express each value in exponential form. Where...Ch. 1 - Express each value in exponential form. Where...Ch. 1 - Indicate whether each of the following is an exact...Ch. 1 - Indicate whether each of the following is an exact...Ch. 1 - Prob. 19ECh. 1 - How many significant figures are shown in each of...Ch. 1 - Perform the following calculations; express each...Ch. 1 - Perform the following calculations; express each...Ch. 1 - Perform the following calculations and retain the...Ch. 1 - Express the result of each of the following...Ch. 1 - An American press release describing the 1986...Ch. 1 - Prob. 26ECh. 1 - Perform the following conversions. a. 0.127L=mL b....Ch. 1 - Prob. 28ECh. 1 - Perform the following from non-SI to SI units....Ch. 1 - Prob. 30ECh. 1 - Which is the greater mass, 3245 (g or 0.00515 mg?...Ch. 1 - Which is the greater mass, 3257 mg or 0.000475 kg?...Ch. 1 - The non-SI unit, hand (used by equestrians), is 4...Ch. 1 - The und furlong is used in horse racing. The unis...Ch. 1 - A sprinter runs the 100 yd dash in 9.3 s. At this...Ch. 1 - A non-SI unit of mass used in Pharmaceutical work...Ch. 1 - Prob. 37ECh. 1 - In an engineering reference book, you find that...Ch. 1 - Prob. 39ECh. 1 - The volumeofaredbloodcell isabout 90.010-12cm3 ....Ch. 1 - We want tomark offathermometer in it Celsius and...Ch. 1 - The highestandlowesttemperatures on record for San...Ch. 1 - The absolute zero of temperature is -273.15C....Ch. 1 - Prob. 44ECh. 1 - Prob. 45ECh. 1 - Prob. 46ECh. 1 - A 2.18 L sample of butyric acid, a substance...Ch. 1 - A 15.2 L sample of chloroform at 20 C has a mass...Ch. 1 - To determine the density of acetone, a 55.0 gal...Ch. 1 - To determine the volume of an irregularly shaped...Ch. 1 - A solution consisting of 8.50% acetone and 91.5%...Ch. 1 - Prob. 52ECh. 1 - A fertilizer contains 21% nitrogen by mass. What...Ch. 1 - A sample is found to have a density of 1.006 g/mL,...Ch. 1 - Prob. 55ECh. 1 - Calculate the mass of a cylinder of stainless...Ch. 1 - The densities are given at 20 C: water, 0.998g/cm3...Ch. 1 - To determine the approximate mass of a small...Ch. 1 - The density of aluminum is 2.70 g/ cm3. A square...Ch. 1 - The angle iron pictured here is made of steel with...Ch. 1 - In normal blood, there are about 5.4109 red blood...Ch. 1 - A technique once used by geologists to measure the...Ch. 1 - In a class of 76 students, the results of...Ch. 1 - A class of 84 students had a final grade...Ch. 1 - Prob. 65ECh. 1 - A solution containing 12.0% sodium hydroxide by...Ch. 1 - According to the rules on significant figures, the...Ch. 1 - Prob. 68IAECh. 1 - A solution used to chlorinate a home swimming pool...Ch. 1 - A standard 1.000 kg mass is to be tut from a bar...Ch. 1 - Prob. 71IAECh. 1 - Prob. 72IAECh. 1 - Magnesium occurs in seawater to the extent of 1.4...Ch. 1 - A typical rate of deposit of dust ("dustfall")...Ch. 1 - In the United States, the volume of irrigation...Ch. 1 - A Fahrenheit and a Celsius thermometer are...Ch. 1 - The accompanying illustration shows e 100.0 mL...Ch. 1 - Prob. 78IAECh. 1 - Prob. 79IAECh. 1 - A pycnometer (see Exercise 78) weighs 25.60 g...Ch. 1 - The Greater Vancouver Regional District (GVRO)...Ch. 1 - A Boeing 767 due to fly from Montreal to Edmonton...Ch. 1 - The following equation can be used to relate the...Ch. 1 - Prob. 84IAECh. 1 - A tabulation of datalists the following equation...Ch. 1 - The total volume of ice in the Antarctic is about...Ch. 1 - An empty 3.00 L bottle weighs 1.70 kg. Fled with...Ch. 1 - The filament in an incandescent light bulb is made...Ch. 1 - Blood alcohol content (BAC) is sometimes reported...Ch. 1 - In an attempt to determine any possible...Ch. 1 - Prob. 91FPCh. 1 - Prob. 92FPCh. 1 - The canoe gliding gracefully along the water in...Ch. 1 - The accompanying sketches suggest four...Ch. 1 - As mentioned on page 13, the MCO was lost because...Ch. 1 - In your own words, define or explain the following...Ch. 1 - Prob. 97SAECh. 1 - Explain the important distinctions between each...Ch. 1 - A procedure designed to test the truth or the...Ch. 1 - The fact that the volume of a fixed amount of gas...Ch. 1 - If a sample of matter cannotbe separated by...Ch. 1 - A good example of a homogeneous mixture is a. a...Ch. 1 - Compared withits mass on Earth, the mass of the...Ch. 1 - Which answer has the correct number of significant...Ch. 1 - Which two of the following masses are expressed to...Ch. 1 - Prob. 106SAECh. 1 - Prob. 107SAECh. 1 - Prob. 108SAECh. 1 - The density of water is 0.9982 g/cm2 at 20C....Ch. 1 - Two students each made four measurements of the...Ch. 1 - Prob. 111SAECh. 1 - List the blowing the order of increasing...Ch. 1 - Without doing detailed calculations, explain which...Ch. 1 - Prob. 114SAECh. 1 - Water, acompound, is a substance. Is there any...Ch. 1 - In the production of ammonia, the...Ch. 1 - Appendix E descries a useful study aid known as...
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