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Chapter 1, Problem 22E

A chemist decomposes several samples of water into hydrogen and oxygen and measures the mass of the hydrogen and the oxygen obtained. The results are tabulated as follows.

Sample Number Grams of Hydrogen Grams of Oxygen
1 1.5 12
2 2 16
3 2.5 20

a. Summarize these observations in a short statement.

Next, the chemist decomposes several samples of carbon dioxide into carbon and oxygen. The results are tabulated as follows:

Sample Number Grams of Hydrogen Grams of Oxygen
1 0.5 1.3
2 1.0 2.7
3 1.5 4.0

b. Summarize these observations in a short statement.

c. Formulate a law from the observations in (a) and (b).

d. Formulate a theory that might explain your law in (c).

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9. The following reaction, which proceeds via the SN1/E1 mechanisms, gives three alkene products (A, B, C) as well as an ether (D). (a) Show how each product arises mechanistically. (b) For the alkenes, determine the major product and justify your answer. (c) What clues in the reaction as shown suggest that this reaction does not go by the SN2/E2 mechanism route? (CH3)2CH-CH-CH3 CH3OH 1 Bl CH3OH ⑧· (CH3)2 CH-CH=CH2 heat H ⑥③ (CH3)2 C = C = CH3 © СнЗ-С-Снаснз сна (CH 3 ) 2 C H G H CH 3 оснз
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Chapter 1 Solutions

Introductory Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Introductory Chemistry Package

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