Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 1, Problem 20E
Interpretation Introduction
Interpretation:
The given image is to be flipped upside down.
Concept introduction:
The flipping of any image is done by keeping the central point of the image fixed. This gives the mirror image view of the image. The flipping can be done horizontally or vertically by choosing the axis around which the image has to be flipped.
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Considering the important roles of biothiols in lysosomes of live organisms, and unique photophysical / photochemical properties of ruthenium(II) complexes, a novel ruthenium(II) complex, Ru-2, has been developed as a molecular probe for phosphorescence and time-gated luminescence assay of biothiols in human sera, live cells, and in vivo. Ru-2 is weakly luminescent due to the effective photoinduced electron transfer (PET) from Ru(II) luminophore to electron acceptor, 2,4-dinitrobenzene-sulfonyl (DNBS). In the presence of biothiols, such as glutathione (GSH), cysteine (Cys), and homocysteine (Hcy), the emission of Ru-2 solution was switched ON, as a result of the cleavage of quencher to form the product, Ru-1. Ru-2 showed high selectivity and sensitivity for the detection of biothiols under physiological conditions, with detection limits of 62 nM, 146 nM, and 115 nM for GSH, Cys, and Hcy, respectively. The emission lifetimes of Ru-1 and Ru-2 were measured to be 405 and 474 ns,…
Chapter 1 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 1 - Prob. 1.1CECh. 1 - Prob. 1.2CECh. 1 - Prob. 1KTCh. 1 - Prob. 2KTCh. 1 - Prob. 3KTCh. 1 - Prob. 4KTCh. 1 - Prob. 5KTCh. 1 - Prob. 6KTCh. 1 - Prob. 7KTCh. 1 - Prob. 8KT
Ch. 1 - Prob. 9KTCh. 1 - Prob. 10KTCh. 1 - Prob. 11KTCh. 1 - Prob. 12KTCh. 1 - Prob. 1ECh. 1 - Prob. 2ECh. 1 - Prob. 3ECh. 1 - Prob. 4ECh. 1 - Prob. 5ECh. 1 - Prob. 6ECh. 1 - Prob. 7ECh. 1 - Prob. 8ECh. 1 - Prob. 9ECh. 1 - Prob. 10ECh. 1 - Prob. 11ECh. 1 - Prob. 12ECh. 1 - Prob. 13ECh. 1 - Prob. 14ECh. 1 - Prob. 15ECh. 1 - Prob. 16ECh. 1 - Prob. 17ECh. 1 - Prob. 18ECh. 1 - Prob. 19ECh. 1 - Prob. 20ECh. 1 - Prob. 1STCh. 1 - Prob. 2STCh. 1 - Prob. 3STCh. 1 - Prob. 4STCh. 1 - Prob. 5STCh. 1 - Prob. 6ST
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