EBK INTRODUCTORY CHEMISTRY
EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Chapter 1, Problem 17QAP

Students approaching the study of chemistry must learn certain basic facts (such as the names and symbols of the most common elements), but it is much more important that they learn to think critically and to go beyond the specific examples discussed in class or in the textbook. Explain how learning to do this might be helpful in any career, even one far removed from chemistry.

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4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be catalyzed the propylene molecules must first adsorb onto the surface. In order to completely cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner 2. (a) Many main group oxides form acidic solutions when added to water. For example solid tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced chemical equation for this reaction. (b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-) and carbon monoxide. Write a balanced chemical equation for this reaction.

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EBK INTRODUCTORY CHEMISTRY

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