CHEMISTRY-W/MASTERING CHEMISTRY ACCESS
8th Edition
ISBN: 9780135205068
Author: Robinson
Publisher: PEARSON
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Chapter 1, Problem 1.62SP
What is the difference between a derived SI unit and a fundamental SI unit? Give an example of each.
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Predicting the pr
Predict the major products of the following organic reaction:
Δ
Some important notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are
enantiomers.
?
Click and drag to start drawing a structure.
propose synthesis
Explanation
O Conjugated Pi Systems
Deducing the reactants of a Diels-Alder reaction
Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one
step, by moderately heating the reactants?
?
Δ
If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any
arrangement you like.
• If your answer is no, check the box under the drawing area instead.
Click and drag to start drawing a structure.
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Chapter 1 Solutions
CHEMISTRY-W/MASTERING CHEMISTRY ACCESS
Ch. 1 - Express the diameter of a nanoparticle(0.000 000...Ch. 1 - APPLY 1.2 Express the following quantities in...Ch. 1 - PRACTICE 1.3 The melting point of table salt is...Ch. 1 - Prob. 1.4ACh. 1 - PRACTICE 1.5 Chloroform, a substance once used as...Ch. 1 - APPLY 1.6 You are beachcombing on summer vacation...Ch. 1 - PRACTICE 1.7 Some radioactive materials emit a...Ch. 1 - Prob. 1.8ACh. 1 - How many significant figures does each of the...Ch. 1 - Read the volume of the buret and reportyour answer...
Ch. 1 - Examine the figure in Worked Example 1.6. Which...Ch. 1 - A 1.000 mL sample of acetone, a common solvent...Ch. 1 - Carry out the following calculations, expressing...Ch. 1 - APPLY 1.14 A sodium chloride solution was prepared...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - The maximum dimensions of a soccer field are 90.0...Ch. 1 - APPLY 1.18 How large, in cubic centimeters, is the...Ch. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Use Figure 1.10 to estimate in powers of 10 (a)...Ch. 1 - On the nanoscale, materials often exhibit...Ch. 1 - Refer to Figure 1.11. Which cube has a...Ch. 1 - Catalytic converters use nanoscale particles of...Ch. 1 - Platinum is an expensive and rare metal used...Ch. 1 - Prob. 1.26PCh. 1 - Which block in each of the following drawings of a...Ch. 1 - Prob. 1.28CPCh. 1 - How many milliliters of water does the graduated...Ch. 1 - Assume that you have two graduated cylinders, one...Ch. 1 - The following cylinder contains three liquids that...Ch. 1 - The following statements pertain to the...Ch. 1 - The following statements pertain to the...Ch. 1 - Label the following statements about the world’s...Ch. 1 - Label the following statements as quantitative or...Ch. 1 - Refer to Figure 1.2. What is developed when...Ch. 1 - What is the difference between a hypothesis and...Ch. 1 - What SI units are used for measuring the following...Ch. 1 - Prefixes for multiples of SI units are used to...Ch. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Bottles of wine sometimes carry the notation...Ch. 1 - Which quantity in each of the following pairs is...Ch. 1 - Which quantity in each of the following pairs is...Ch. 1 - How many picograms are in 1 mg? In 35 ng?Ch. 1 - How many microliters are in 1 L? In 20 mL?Ch. 1 - Prob. 1.47SPCh. 1 - Express the following measurements in scientific...Ch. 1 - Convert the following measurements from scientific...Ch. 1 - An experimental procedure call for 250 mg of...Ch. 1 - A virus has a diameter of 5.2108m . What is the...Ch. 1 - Which is larger, a Fahrenheit degree or a Celsius...Ch. 1 - What is the difference between a kelvin and a...Ch. 1 - The normal body temperature of a goat is 39.9 °C,...Ch. 1 - Of the 90 or so naturally occurring elements, only...Ch. 1 - Suppose that your oven is calibrated in degrees...Ch. 1 - Tungsten, the element used to make filaments in...Ch. 1 - Suppose you were dissatisfied with both Celsius...Ch. 1 - Answer parts (a)(d) of Problem 1.58 assuming that...Ch. 1 - Sodium chloride has a melting point of 1074 K and...Ch. 1 - A 125 mL sample of water at 293.2 K was heated for...Ch. 1 - What is the difference between a derived SI unit...Ch. 1 - Which volume in each pair is larger, and by...Ch. 1 - What is the volume in L of a cube with an edge...Ch. 1 - What is the volume in mL of a cube with an edge...Ch. 1 - What is the density of glass in g/cm3 if a sample...Ch. 1 - What is the density of lead in g/cm3 if a sample...Ch. 1 - A vessel contains 4.67 L of bromine whose density...Ch. 1 - Aspirin has a density of 1.40g/cm3 . What is the...Ch. 1 - Gaseous hydrogen has a density of 0.0899 g/L at...Ch. 1 - The density of silver is 10.5g/cm3 . What is the...Ch. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - You would like to determine if a set of antique...Ch. 1 - An experiment is performed to determine if pennies...Ch. 1 - The density of chloroform, a widely used organic...Ch. 1 - More sulfuric acid (density=1.8302g/cm3) is...Ch. 1 - Prob. 1.78SPCh. 1 - Assume that the kinetic energy of a 1400 kg car...Ch. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Prob. 1.83SPCh. 1 - Prob. 1.84SPCh. 1 - What is the difference in mass between a nickel...Ch. 1 - How many significant figures are in each of the...Ch. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - The diameter of the Earth at the equator is...Ch. 1 - Round off the following quantities to the number...Ch. 1 - Round off the following quantities to the number...Ch. 1 - Express the results of the following calculations...Ch. 1 - Express the results of the following calculations...Ch. 1 - Carry out the following conversions. (a) How many...Ch. 1 - Convert the following quantities into SI units...Ch. 1 - Prob. 1.96SPCh. 1 - In the United States, the emissions limit for...Ch. 1 - Prob. 1.98SPCh. 1 - Prob. 1.99SPCh. 1 - Prob. 1.100SPCh. 1 - Concentrations of substances dissolved in solution...Ch. 1 - Prob. 1.102SPCh. 1 - Prob. 1.103SPCh. 1 - Which is larger in each pair, and by approximate...Ch. 1 - The density of polystyrene, a plastic commonly...Ch. 1 - The density of polypropylene, a plastic commonly...Ch. 1 - Prob. 1.107MPCh. 1 - A 1.0-ounce piece of chocolate contains 15 mg of...Ch. 1 - Prob. 1.109MPCh. 1 - Prob. 1.110MPCh. 1 - Prob. 1.111MPCh. 1 - A bag of Hershey’s Kisses contains the following...Ch. 1 - Vinaigrette salad dressing consists mainly of oil...Ch. 1 - At a certain point, the Celsius and Fahrenheit...Ch. 1 - Prob. 1.115MPCh. 1 - A calibrated flask was filled to the 25.00 mL mark...Ch. 1 - Brass is a copper-zinc alloy. What is the mass in...Ch. 1 - Ocean currents are measured in Sverdrups (sv)...Ch. 1 - The element gallium (Ga) has the second-largest...
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- Diels Alder Cycloaddition: Focus on regiochemistry (problems E-F) –> match + of thedienophile and - of the diene while also considering stereochemistry (endo).arrow_forwardHELP! URGENT! PLEASE RESOND ASAP!arrow_forwardQuestion 4 Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267 First-order, k = 0.210 hour 1 First-order, k = 0.0912 hour 1 O Second-order, k = 0.590 M1 hour 1 O Zero-order, k = 0.0770 M/hour O Zero-order, k = 0.4896 M/hour O Second-order, k = 1.93 M-1-hour 1 10 ptsarrow_forward
- Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267arrow_forwardDraw the products of the reaction shown below. Use wedge and dash bonds to indicate stereochemistry. Ignore inorganic byproducts. OSO4 (cat) (CH3)3COOH Select to Draw ઘarrow_forwardCalculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forward
- Problem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forward
- Steps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forwardSteps and explanationn please.arrow_forward
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