To draw: The structure of the given compound with the proper representation of pi bond and geometry. Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn. Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

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Answer 1

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 3

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 4

Question

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

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Answer 5

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 6

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 7

Chapter 1, Problem 1.56SP

(a)

Interpretation Introduction

To draw: The structure of the given compound with the proper representation of pi bond and geometry.

Interpretation: The structure of the given compound with the proper representation of pi bond and geometry is to be drawn.

Concept introduction: Isomers are the compounds with similar formula but different structures. Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 8

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 9

(b)

Interpretation Introduction

To determine: The six coplanar atoms in the given compound.

Interpretation: Six coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 10

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 11

(c)

Interpretation Introduction

To draw: The structure of the trans isomer of the given compound with circled coplanar atoms and if there are still six coplanar atoms.

Interpretation: The structure of the trans isomer of the given compound with circled coplanar atoms is to be drawn and the existence of six coplanar atoms is to be validated.

Concept introduction: Stereoisomers are the type of isomers in which arrangement of atoms differ in space. Geometric isomers are one of the types of stereoisomers. These are of two types and are named as, cis and trans isomers. These types of isomers generate due to the restricted rotations around the carbon-carbon double bond within the molecule.

Answer 12

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 13

(d)

Interpretation Introduction

To determine: The representation of circled coplanar atoms in the given compound.

Interpretation: The coplanar atoms in the given compound are to be circled.

Concept introduction: Carbon –carbon double bonds exist in the same plane. Hydrogen or any other group also lies in the same plane to satisfy its valency. In the given compound, sp2 hybridization is present. In this type of hybridization, all the groups lie in the same plane.

Answer 14

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Answer 16

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Answer 17

Ch. 1.2C - a. Nitrogen has relatively stable isotopes...Ch. 1.4 - Draw Lewis structures for the following compounds....Ch. 1.5 - Write Lewis structures for the following molecular...Ch. 1.5 - Circle any lone pairs (pairs of nonbonding...Ch. 1.6 - Use electronegativities to predict the direction...Ch. 1.8 - Prob. 1.6P Ch. 1.9B - Draw the important resonance forms for the...Ch. 1.9B - Prob. 1.8P Ch. 1.9B - Prob. 1.9P Ch. 1.9B - Use resonance structures to identify the areas of...

Solution Summary: The author explains the structure of the compound with the proper representation of pi bond and geometry.

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