Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 1, Problem 1.32SP

(a)

Interpretation Introduction

To determine: The Lewis structure of the compound CH3COCH2CHCHCOOH.

Interpretation: The Lewis structure of the compound CH3COCH2CHCHCOOH is to be drawn.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines and the lone pair of electrons is shown by a pair of dots.

The rules to draw Lewis structure are given as,

  • Determine the electronegativity and the number of valence electrons contributed by each atom.
  • Generally lowest electronegativity atom is the central atom.
  • Write the skeleton structure of the molecule.
  • Use two valence electrons to form each bond in skeleton structure between the central and outer atoms.
  • Satisfy the octets of atoms by distributing remaining valence electrons as nonbonding electrons. It is usually best start with the outer atoms.

(b)

Interpretation Introduction

To determine: The Lewis structure of the compound NCCH2COCH2CHO.

Interpretation: The Lewis structure of the compound NCCH2COCH2CHO is to be drawn.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines and the lone pair of electrons is shown by a pair of dots.

The rules to draw Lewis structure are given as,

  • Determine the electronegativity and the number of valence electrons contributed by each atom.
  • Generally lowest electronegativity atom is the central atom.
  • Write the skeleton structure of the molecule.
  • Use two valence electrons to form each bond in skeleton structure between the central and outer atoms.
  • Satisfy the octets of atoms by distributing remaining valence electrons as nonbonding electrons. It is usually best start with the outer atoms.

(c)

Interpretation Introduction

To determine: The Lewis structure of the compound CH2CHCH(OH)CH2CO2H.

Interpretation: The Lewis structure of the compound CH2CHCH(OH)CH2CO2H is to be drawn.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines and the lone pair of electrons is shown by a pair of dots.

The rules to draw Lewis structure are given as,

  • Determine the electronegativity and the number of valence electrons contributed by each atom.
  • Generally lowest electronegativity atom is the central atom.
  • Write the skeleton structure of the molecule.
  • Use two valence electrons to form each bond in skeleton structure between the central and outer atoms.
  • Satisfy the octets of atoms by distributing remaining valence electrons as nonbonding electrons. It is usually best start with the outer atoms.

(d)

Interpretation Introduction

To determine: The Lewis structure of the compound CH2CHCH(OH)CH2CO2H.

Interpretation: The Lewis structure of the compound CH2CHCH(OH)CH2CO2H is to be drawn.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines and the lone pair of electrons is shown by a pair of dots.

The rules to draw Lewis structure are given as,

  • Determine the electronegativity and the number of valence electrons contributed by each atom.
  • Generally lowest electronegativity atom is the central atom.
  • Write the skeleton structure of the molecule.
  • Use two valence electrons to form each bond in skeleton structure between the central and outer atoms.
  • Satisfy the octets of atoms by distributing remaining valence electrons as nonbonding electrons. It is usually best start with the outer atoms.

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI.  AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at.  All of these compounds would be produced (I think).  In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason.  Please explain why some of these produce less yield than others.

Chapter 1 Solutions

Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition

Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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