CHEMISTRY 1111 LAB MANUAL >C<
1st Edition
ISBN: 9781307092097
Author: Chang
Publisher: MCG/CREATE
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Chapter 1, Problem 1.54QP
Which of the following statements describe physical properties and which describe chemical properties? (a) Iron has a tendency to rust. (b) Rainwater in industrialized regions tends to be acidic. (c) Hemoglobin molecules have a red color. (d) When a glass of water is left out in the sun, the water gradually disappears. (e) Carbon dioxide in air is converted to more complex molecules by plants during photosynthesis.
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 1 Solutions
CHEMISTRY 1111 LAB MANUAL >C<
Ch. 1.3 - Which of the following statements is true? (a) A...Ch. 1.4 - Which of the following diagrams represent elements...Ch. 1.5 - An ice cube is placed in a closed container. On...Ch. 1.6 - The diagram in (a) shows a compound made up of...Ch. 1.7 - A piece of platinum metal with a density of 21.5...Ch. 1.7 - The density of sulfuric acid in a certain car...Ch. 1.7 - Convert (a) 327.5C (the melting point of lead) to...Ch. 1.7 - The density of copper is 8.94 g/cm3 at 20C and...Ch. 1.8 - Determine the number of significant figures in...Ch. 1.8 - Carry out the following arithmetic operations and...
Ch. 1.8 - Give the length of the pencil with proper...Ch. 1.9 - A roll of aluminum foil has a mass of 1.07 kg....Ch. 1.9 - The volume of a room is 1.08 108 dm3. What is the...Ch. 1.9 - The density of the lightest metal, lithium (Li),...Ch. 1.9 - Review of Concepts
The Food and Drug...Ch. 1.10 - Prob. 9PECh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between qualitative data...Ch. 1 - Classify the following as qualitative or...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - Give an example of a homogeneous mixture and an...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Give an example of an element and a compound. 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Discuss the importance...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.30QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Express the answers to the following calculations...Ch. 1 - Prob. 1.33QPCh. 1 - How many significant figures are there in each of...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Three apprentice tailors (X, Y, and Z) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - How many seconds are there in a solar year (365.24...Ch. 1 - Prob. 1.43QPCh. 1 - A jogger runs a mile in 8.92 min. Calculate the...Ch. 1 - A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - The speed limit on parts of the German autobahn...Ch. 1 - Prob. 1.47QPCh. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Carry out the following conversions: (a) 70 kg,...Ch. 1 - Aluminum is a lightweight metal (density = 2.70...Ch. 1 - Ammonia gas is used as a refrigerant in...Ch. 1 - Prob. 1.53QPCh. 1 - Which of the following statements describe...Ch. 1 - Prob. 1.55QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - A cylindrical glass bottle 21.5 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - Prob. 1.60QPCh. 1 - A piece of silver (Ag) metal weighing 194.3 g is...Ch. 1 - Prob. 1.62QPCh. 1 - A lead sphere of diameter 48.6 cm has a mass of...Ch. 1 - Lithium is the least dense metal known (density:...Ch. 1 - Prob. 1.65QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 1.68QPCh. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - (a) Referring to Problem 1.71, calculate the total...Ch. 1 - Three different 25.0-g samples of solid pellets...Ch. 1 - Prob. 1.72QPCh. 1 - Prob. 1.73QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - The unit troy ounce is often used for precious...Ch. 1 - Prob. 1.76QPCh. 1 - Prob. 1.77QPCh. 1 - The natural abundances of elements in the human...Ch. 1 - The mens world record for running a mile outdoors...Ch. 1 - Prob. 1.80QPCh. 1 - Chalcopyrite, the principal ore of copper (Cu),...Ch. 1 - Prob. 1.82QPCh. 1 - Prob. 1.83QPCh. 1 - Measurements show that 1.0 g of iron (Fe) contains...Ch. 1 - The thin outer layer of Earth, called the crust,...Ch. 1 - Prob. 1.86QPCh. 1 - One gallon of gasoline in an automobiles engine...Ch. 1 - A sheet of aluminum (Al) foil has a total area of...Ch. 1 - Prob. 1.89QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - An aluminum cylinder is 10.0 cm in length and has...Ch. 1 - Prob. 1.92QPCh. 1 - Prob. 1.93QPCh. 1 - Prob. 1.94QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Prob. 1.96QPCh. 1 - A bank teller is asked to assemble one-dollar sets...Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - Prob. 1.99QPCh. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Tums is a popular remedy for acid indigestion. A...Ch. 1 - A 250-mL glass bottle was filled with 242 mL of...Ch. 1 - What is the mass of one mole of ants? 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