CHEMISTRY 1111 LAB MANUAL >C<
1st Edition
ISBN: 9781307092097
Author: Chang
Publisher: MCG/CREATE
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Textbook Question
Chapter 1, Problem 1.109IME
Fusing “nanofibers” with diameters of 100 to 300 nm gives junctures with very small volumes that would potentially allow the study of reactions involving only a few molecules. Estimate the volume in liters of the junction formed between two such fibers with internal diameters of 200 nm. The scale reads 1 μm.
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Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 1 Solutions
CHEMISTRY 1111 LAB MANUAL >C<
Ch. 1.3 - Which of the following statements is true? (a) A...Ch. 1.4 - Which of the following diagrams represent elements...Ch. 1.5 - An ice cube is placed in a closed container. On...Ch. 1.6 - The diagram in (a) shows a compound made up of...Ch. 1.7 - A piece of platinum metal with a density of 21.5...Ch. 1.7 - The density of sulfuric acid in a certain car...Ch. 1.7 - Convert (a) 327.5C (the melting point of lead) to...Ch. 1.7 - The density of copper is 8.94 g/cm3 at 20C and...Ch. 1.8 - Determine the number of significant figures in...Ch. 1.8 - Carry out the following arithmetic operations and...
Ch. 1.8 - Give the length of the pencil with proper...Ch. 1.9 - A roll of aluminum foil has a mass of 1.07 kg....Ch. 1.9 - The volume of a room is 1.08 108 dm3. What is the...Ch. 1.9 - The density of the lightest metal, lithium (Li),...Ch. 1.9 - Review of Concepts
The Food and Drug...Ch. 1.10 - Prob. 9PECh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between qualitative data...Ch. 1 - Classify the following as qualitative or...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - Give an example of a homogeneous mixture and an...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Give an example of an element and a compound. How...Ch. 1 - What is the number of known elements?Ch. 1 - Do the following statements describe chemical or...Ch. 1 - Does each of the following describe a physical...Ch. 1 - Give the names of the elements represented by the...Ch. 1 - Give the chemical symbols for the following...Ch. 1 - Classify each of the following substances as an...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for density of...Ch. 1 - Describe the three temperature scales used in the...Ch. 1 - Bromine is a reddish-brown liquid. Calculate its...Ch. 1 - The density of methanol, a colorless organic...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - Prob. 1.24QPCh. 1 - Convert the following temperatures to kelvin: (a)...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - What is the advantage of using scientific notation...Ch. 1 - Define significant figure. Discuss the importance...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.30QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Express the answers to the following calculations...Ch. 1 - Prob. 1.33QPCh. 1 - How many significant figures are there in each of...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Carry out the following operations as if they were...Ch. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Three apprentice tailors (X, Y, and Z) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - How many seconds are there in a solar year (365.24...Ch. 1 - Prob. 1.43QPCh. 1 - A jogger runs a mile in 8.92 min. Calculate the...Ch. 1 - A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - The speed limit on parts of the German autobahn...Ch. 1 - Prob. 1.47QPCh. 1 - Prob. 1.48QPCh. 1 - Prob. 1.49QPCh. 1 - Carry out the following conversions: (a) 70 kg,...Ch. 1 - Aluminum is a lightweight metal (density = 2.70...Ch. 1 - Ammonia gas is used as a refrigerant in...Ch. 1 - Prob. 1.53QPCh. 1 - Which of the following statements describe...Ch. 1 - Prob. 1.55QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - A cylindrical glass bottle 21.5 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - Prob. 1.60QPCh. 1 - A piece of silver (Ag) metal weighing 194.3 g is...Ch. 1 - Prob. 1.62QPCh. 1 - A lead sphere of diameter 48.6 cm has a mass of...Ch. 1 - Lithium is the least dense metal known (density:...Ch. 1 - Prob. 1.65QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 1.68QPCh. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - (a) Referring to Problem 1.71, calculate the total...Ch. 1 - Three different 25.0-g samples of solid pellets...Ch. 1 - Prob. 1.72QPCh. 1 - Prob. 1.73QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - The unit troy ounce is often used for precious...Ch. 1 - Prob. 1.76QPCh. 1 - Prob. 1.77QPCh. 1 - The natural abundances of elements in the human...Ch. 1 - The mens world record for running a mile outdoors...Ch. 1 - Prob. 1.80QPCh. 1 - Chalcopyrite, the principal ore of copper (Cu),...Ch. 1 - Prob. 1.82QPCh. 1 - Prob. 1.83QPCh. 1 - Measurements show that 1.0 g of iron (Fe) contains...Ch. 1 - The thin outer layer of Earth, called the crust,...Ch. 1 - Prob. 1.86QPCh. 1 - One gallon of gasoline in an automobiles engine...Ch. 1 - A sheet of aluminum (Al) foil has a total area of...Ch. 1 - Prob. 1.89QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - An aluminum cylinder is 10.0 cm in length and has...Ch. 1 - Prob. 1.92QPCh. 1 - Prob. 1.93QPCh. 1 - Prob. 1.94QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Prob. 1.96QPCh. 1 - A bank teller is asked to assemble one-dollar sets...Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - Prob. 1.99QPCh. 1 - Prob. 1.100QPCh. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Tums is a popular remedy for acid indigestion. A...Ch. 1 - A 250-mL glass bottle was filled with 242 mL of...Ch. 1 - What is the mass of one mole of ants? (Useful...Ch. 1 - How much time (in years) does an So-year-old...Ch. 1 - Estimate the daily amount of water (in gallons)...Ch. 1 - Public bowling alleys generally stock bowling...Ch. 1 - Fusing nanofibers with diameters of 100 to 300 nm...Ch. 1 - Prob. 1.110IMECh. 1 - Estimate the total amount of ocean water in...Ch. 1 - Estimate the volume of blood in an adult in...Ch. 1 - Prob. 1.113IMECh. 1 - Estimate the distance (in miles) covered by an NBA...Ch. 1 - In water conservation, chemists spread a thin film...
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