CHEM 212:STUDENT SOLUTION MANUAL
8th Edition
ISBN: 9781260304473
Author: SILBERBERG
Publisher: MCGRAW-HILL CUSTOM PUBLISHING
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Question
Chapter 1, Problem 1.47P
Interpretation Introduction
Interpretation:
The volume
Concept introduction:
Volume is a physical quantity and its SI unit is cubic meter
The formula to calculate the volume of a cylinder is,
Here,
The relation between diameter and radius is,
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 1 Solutions
CHEM 212:STUDENT SOLUTION MANUAL
Ch. 1.1 - Is the following change chemical or physical?
Ch. 1.1 - Is the following change chemical or physical?
Ch. 1.1 - Decide whether each of the following processes is...Ch. 1.1 - Decide whether each of the following processes is...Ch. 1.4 - A chemistry professor can walk a mile in 15...Ch. 1.4 - The rhinovirus, one cause of the common cold, has...Ch. 1.4 - Prob. 1.4AFPCh. 1.4 - Prob. 1.4BFPCh. 1.4 - An intravenous nutrient solution is delivered to a...Ch. 1.4 - Nutritional tables give the potassium content of a...
Ch. 1.4 - A landowner wants to spray herbicide on a field...Ch. 1.4 - Prob. 1.6BFPCh. 1.4 - Prob. 1.7AFPCh. 1.4 - Prob. 1.7BFPCh. 1.4 - Mercury melts at 234 K, lower than any other pure...Ch. 1.4 - Prob. 1.8BFPCh. 1.5 - For each of the following quantities, underline...Ch. 1.5 - Prob. 1.9BFPCh. 1.5 - Prob. 1.10AFPCh. 1.5 - Prob. 1.10BFPCh. 1 - Prob. 1.1PCh. 1 - Describe solids, liquids, and gases in terms of...Ch. 1 - Use your descriptions from Problem 1.2 to identify...Ch. 1 - Define physical property and chemical property....Ch. 1 - Prob. 1.5PCh. 1 - Which of the following is a chemical change?...Ch. 1 - Which of the following changes can be reversed by...Ch. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - The alchemical, medical, and technological...Ch. 1 - How did the phlogiston theory explain combustion?
Ch. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - For each of the following cases, state whether the...Ch. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Prob. 1.24PCh. 1 - Prob. 1.25PCh. 1 - Prob. 1.26PCh. 1 - Prob. 1.27PCh. 1 - What is the length in inches (in) of a 100.-m...Ch. 1 - Prob. 1.29PCh. 1 - Prob. 1.30PCh. 1 - Prob. 1.31PCh. 1 - Prob. 1.32PCh. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - The speed of light in a vacuum is 2.998 × 108 m/s....Ch. 1 - Prob. 1.36PCh. 1 - Prob. 1.37PCh. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - A small cube of aluminum measures 15.6 mm on a...Ch. 1 - A steel ball-bearing with a circumference of 32.5...Ch. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - A 25.0-g sample of each of three unknown metals is...Ch. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Prob. 1.47PCh. 1 - Prob. 1.48PCh. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - Round off each number in the following calculation...Ch. 1 - Prob. 1.57PCh. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Write the following numbers in scientific...Ch. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Which of the following include exact numbers?
The...Ch. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - The following dartboards illustrate the types of...Ch. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Bromine is used to prepare the pesticide methyl...Ch. 1 - Prob. 1.77PCh. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - Prob. 1.82PCh. 1 - Prob. 1.83PCh. 1 - Prob. 1.84PCh. 1 - Prob. 1.85PCh. 1 - Prob. 1.86P
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