Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
12th Edition
ISBN: 9780321908445
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 1, Problem 1.46AQAP
Interpretation Introduction
Interpretation: The percentage of students who received B’s and C’s.
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- Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the number
corresponding to the compound's relative rank in the blank below the structure.
a.
NO₂
NO₂
CH2CH2CH2CH2OH
CH3 CH3CH2CHOH
CH3CH2CH2CH2OH
NO₂
CH3CHCH2CH2OH
b.
OH
OH
CH₂OH
CO₂H
HC
CN
CN
CN
Give the major organic product(s) of the following reactions or sequences of reactions. Show all
relevant stereochemistry
a.
H
MgBr
1. ether
2. H₂O*
4
COH
b.
1. LIAIH, ether
2. H₂O
Choose the best reagent(s) for carrying out the following conversions from the list provided below.
Place the letter of the best choice in the blank to the left of the conversion. Reagents may be used
more than once.
a. 1.
CH3MgBr, ether
2. H3O+
NaOH
b. 1.
PBr3
2.
C.
2.
1. (CH3)3SiCl, (CH3CH2)3N
CH3MgBr, ether
3. H₂O*+
2. H3O+
e. 1. p-TosCl, pyridine
f.
نها
g.
2. NaOH
CrO3, H₂SO4, H₂O
1.
NaBH4, ethanol
2. H30*
h. PCC, CH2Cl2
Ovoldo-6
a.
b.
OH
OH
H
OH
O
any organic
Determine the rate law for sodium thiosulfate from the following data:
[Na2S2O3] Time (s)
0.0318 230.
0.0636 57.5
Chapter 1 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
Ch. 1.1 - Write a one-sentence definition for each of the...Ch. 1.1 - Ask two of your friends (not in class) to define...Ch. 1.1 - Obtain a bottle of multivitamins and read the list...Ch. 1.1 - Prob. 1.4QAPCh. 1.1 - Read the labels on some items found in your...Ch. 1.1 - Read the labels on products used to wash your...Ch. 1.2 - Prob. 1.7QAPCh. 1.2 - Identify each of the following as an observation,...Ch. 1.2 - 1.7 Identify each activity, a to f, as...Ch. 1.2 - Identify each activity, a to f as an observation,...
Ch. 1.3 - Prob. 1.11QAPCh. 1.3 - What are four things that would make it difficult...Ch. 1.3 - Prob. 1.13QAPCh. 1.3 - Prob. 1.14QAPCh. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - What is the place value for the bold digit? a....Ch. 1.4 - 1.17 Evaluate each of the following:
a.
b.
c.
Ch. 1.4 - Prob. 1.18QAPCh. 1.4 - Prob. 1.19QAPCh. 1.4 - Prob. 1.20QAPCh. 1.4 - 1.21 Solve each of the following for a:
a.
b.
Ch. 1.4 - 1.2 Ask two of your friends (not in this class) to...Ch. 1.4 - Prob. 1.23QAPCh. 1.4 -
1.24
a. What is measured on the horizontal axis?...Ch. 1.4 - Prob. 1.25QAPCh. 1.4 - Write each of the following in scientific...Ch. 1.4 - Prob. 1.27QAPCh. 1.4 - Prob. 1.28QAPCh. 1 - Prob. 1.29UTCCh. 1 - Prob. 1.30UTCCh. 1 - Prob. 1.31UTCCh. 1 - Prob. 1.32UTCCh. 1 - Prob. 1.33UTCCh. 1 - 1.38 Classify each of the following statements as...Ch. 1 - Prob. 1.35UTCCh. 1 - Prob. 1.36UTCCh. 1 - Prob. 1.37AQAPCh. 1 - Prob. 1.38AQAPCh. 1 - Prob. 1.39AQAPCh. 1 - Prob. 1.40AQAPCh. 1 - Prob. 1.41AQAPCh. 1 - Prob. 1.42AQAPCh. 1 - 1.43 Evaluate each of the following:...Ch. 1 - Prob. 1.44AQAPCh. 1 - A bag of gumdrops contains 16 orange gumdrops, 8...Ch. 1 - Prob. 1.46AQAPCh. 1 - Prob. 1.47AQAPCh. 1 - Prob. 1.48AQAPCh. 1 - Classify each of the following as an observation,...Ch. 1 - Classify each of the following as an observation,...Ch. 1 - Prob. 1.51CQCh. 1 - Solve each of the following for z: (1.4) a....Ch. 1 - Prob. 1.53CQCh. 1 - Prob. 1.54CQ
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- Don't used hand raiting and don't used Ai solutionarrow_forwardDetermine the rate order from the following data: [Na2S2O3] Time (s) 0.0455 M 180.0 0.0909 M 90.0 0.136 M 60.0 Group of answer choices First order Second order Third order Zero orderarrow_forwardWrite down by equation of the following reactions: the Clemmensen reduction and synthesize of a secondary alcarrow_forward
- Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and isomers can be separated. a. b. O₂N- Cl COOH para 0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can be separated a. Br b. COOH CH3 NH₂ PABA (active ingredient in some sunscreens)arrow_forwardH3C H C=C CH3 H m-chloroperoxybenzoic acid CH2Cl2, rt C-C--. H3CH2CC H H3C CH3 Cl₂ H₂O NaOH H₂O D. S- E. CH3 H₂O₂, H₂O It CH₂O Na + CHI F. HI, H₂O heat G. 4 OH CH3CHCH3 + ICH2CH3 1. NaH (CH3)3COH (CH3)3 COCHCH2CH3 2. CH3arrow_forward5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all reagents and all intermediate structures. H3C- H3C- CI OCH2CH3arrow_forward
- Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3arrow_forwardPlease correct answer and don't used hand raitingarrow_forwardTo answer the following questions, consider the reaction below: CH3 . CH3 OH a. The best reagents for accomplishing the above transformation are.... a. 1. OsO4, pyridine 2. NaHSO3, H₂O b. 1. Hg(OAc)2, H₂O 1. C. 2. NaBH4 RCO₂H, CH2Cl₂ 2. H₂O* d. 1. BH3, THF 2. H₂O₂, OH b. The alcohol product is classified as a: a. 1° alcohol b. 2° alcohol C. 3° alcohol d. 4° alcohol c. The conversion of an alcohol into an alkyl chloride by reaction with SOCI2 is an example of: a. b. ن نخنه C. d. an El process an Syl process an E2 process an Sy2 processarrow_forward
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