Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 1, Problem 12CTQ

Consider the following flat drawing of methane ( CH 4 ) .
a. What is HCH bond angle implied by this drawing if you assume it is flat?
Chapter 1, Problem 12CTQ, Consider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this , example  1
b. Are the electron domains of this flat CH 4 spread out as much as possible?
c. Use model materials to make a model of CH 4 (methane). If you assembled it correctly, thefour bonds (bonding electron domains) of your model will be 109.5° apart.
d. In which representation, the drawing above or the model in your hand (circle one) are theH’s of CH 4 more spread out around the central carbon?
e. Confirm that your model looks like the following drawing. The wedgebond represents a bond coming out of the page, and the dash bondrepresents a bond going into the page
f. You will often see methane drawn as if it were flat (like on the previous page). Why is thismisleading, and what is left to the viewer’s imagination when looking at such a drawing?
Chapter 1, Problem 12CTQ, Consider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this , example  2

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Q8. Draw the mechanism for this halogenation reaction. Show all steps including initiation, propagation, and recombination. Cl₂, hv CI Br Br2, hv, heat
Q6. Given the following alkanes, draw the most likely product to form upon monohalogenation with Br2 (keep in mind that this may not be the only product to form though). If the reaction was performed with Cl2 would there be more or less selectivity in the desired product formation? Why? (a) (b) (c)
Q4. Radicals a. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (c) CH3 CH3 H3C CH3 (a) CH3 (b)
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