Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Textbook Question
Chapter 1, Problem 1.106E
The following pairs of substances represent heterogeneous mixtures. For each pair, describe the steps you would follow to separate the components and collect them.
a. wood sawdust and sand
b. sugar and sand
c. iron filings and sand
d. sand soaked with oil
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 1 - A heavy steel ball is suspended by a thin wire....Ch. 1 - Explain how the following are related to each...Ch. 1 - Tell how you would try to prove to a doubter that...Ch. 1 - Prob. 1.4ECh. 1 - The attractive force of gravity for objetcs near...Ch. 1 - Earths rotation causes it to bulge at the equator....Ch. 1 - Classify each of the following as a physical or...Ch. 1 - Classify each of the following as a physical or...Ch. 1 - Classify each of the following properties as...Ch. 1 - Classify each of the following properties as...
Ch. 1 - A sample of liquid alcohol is frozen to a solid,...Ch. 1 - Succinic acid, a white solid that melts at 182C,...Ch. 1 - A sample of solid elemental phosphorus that is...Ch. 1 - Oxygen gas and solid carbon are both made up of...Ch. 1 - Under appropriate conditions, hydrogen peroxide...Ch. 1 - Water can be decomposed to hydrogen gas and oxygen...Ch. 1 - Methane gas, a component of natural gas, is burned...Ch. 1 - Classify each pure substance represented below by...Ch. 1 - Classify each pure substance represented below by...Ch. 1 - Consider the following experiments, and answer the...Ch. 1 - Early scientists incorrectly classified calcium...Ch. 1 - Classify each of the following as homogeneous or...Ch. 1 - Classify each of the following as homogeneous or...Ch. 1 - Classify as pure substance or solution each of the...Ch. 1 - Classify as pure substance or solution each of the...Ch. 1 - Prob. 1.26ECh. 1 - In the distant past, 1in. was defined as the...Ch. 1 - Prob. 1.28ECh. 1 - Which of the following quantities are expressed in...Ch. 1 - Which of the following quantities are expressed in...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Referring only to Table 1.2, answer the following...Ch. 1 - Referring only to Table 1.2, answer the following...Ch. 1 - One inch is approximately equal to 2.54cm. Express...Ch. 1 - Cookbooks are going metric. In such books, 1 cup...Ch. 1 - Two cities in Germany are located 25km apart. What...Ch. 1 - The shotput used by female track and field...Ch. 1 - Referring to Table 1.3, answer the following...Ch. 1 - Prob. 1.40ECh. 1 - Prob. 1.41ECh. 1 - Using appropriate values from Table 1.3, answer...Ch. 1 - Prob. 1.43ECh. 1 - Prob. 1.44ECh. 1 - Prob. 1.45ECh. 1 - Which of the following numbers are written using...Ch. 1 - Which of the following numbers are written using...Ch. 1 - Write each of the following numbers using...Ch. 1 - Write each of the following numbers using...Ch. 1 - Prob. 1.50ECh. 1 - A sheet of paper is 0.0106cm, or 0.0042in., thick....Ch. 1 - Prob. 1.52ECh. 1 - Prob. 1.53ECh. 1 - Do the following multiplications, and express each...Ch. 1 - Prob. 1.55ECh. 1 - Prob. 1.56ECh. 1 - Express each of the following numbers using...Ch. 1 - Prob. 1.58ECh. 1 - Prob. 1.59ECh. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Indicate to what decimal position readings should...Ch. 1 - Indicate to what decimal position readings should...Ch. 1 - Write the following measured quantities as you...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.69ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.71ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.73ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.76ECh. 1 - Determine a single factor derived from Table 1.3...Ch. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Prob. 1.80ECh. 1 - Prob. 1.81ECh. 1 - A metric cookbook calls for 250mL of milk. Your...Ch. 1 - Prob. 1.83ECh. 1 - You have a 40-lb baggage limit for a transatlantic...Ch. 1 - You need 3.00lb of meat that sells for 3.41/lb...Ch. 1 - During a glucose tolerance test, the serum glucose...Ch. 1 - Prob. 1.87ECh. 1 - Prob. 1.88ECh. 1 - Prob. 1.89ECh. 1 - Prob. 1.90ECh. 1 - Prob. 1.91ECh. 1 - Immunoglobulin antibodies occur in five forms. A...Ch. 1 - Calculate the density of the following materials...Ch. 1 - Calculate the density of the following materials...Ch. 1 - Calculate the volume and density of a rectangular...Ch. 1 - Calculate the volume and density of a cube of lead...Ch. 1 - The volume of an irregularly shaped solid can be...Ch. 1 - The density of ether is 0.736g/mL. What is the...Ch. 1 - Calculate the mass in grams of 100.0mL of...Ch. 1 - Do the following metric system conversions by...Ch. 1 - A single water molecule has a mass of 2.991023g....Ch. 1 - Prob. 1.102ECh. 1 - Cooking oil has a density of 0.812g/mL. What is...Ch. 1 - Prob. 1.104ECh. 1 - At 4.0C, pure water has a density of 1.00g/mL. At...Ch. 1 - The following pairs of substances represent...Ch. 1 - Explain why a bathroom mirror becomes foggy when...Ch. 1 - Prob. 1.108ECh. 1 - Liquid mercury metal freezes to a solid at a...Ch. 1 - Prob. 1.110ECh. 1 - Show how the factor-unit method can be used to...Ch. 1 - Prob. 1.112ECh. 1 - Refer to Chemistry Around Us 1.2 and explain what...Ch. 1 - Prob. 1.114ECh. 1 - Which of the following properties is considered a...Ch. 1 - Which of the following properties depicts a...Ch. 1 - Which of the following is a mixture? a.sodium...Ch. 1 - Prob. 1.118ECh. 1 - Prob. 1.119ECh. 1 - The correct formula for converting Fahrenheit to...Ch. 1 - Prob. 1.121ECh. 1 - Prob. 1.122ECh. 1 - Prob. 1.123ECh. 1 - How many millimeters are there in one centimeter?...Ch. 1 - Convert 4.50102nm into pm. a.4.50102pm b.4.50102pm...Ch. 1 - Prob. 1.126ECh. 1 - Convert 4.50102nm into m. a.4.50102m b.4.501011m...Ch. 1 - The quantity 6185meters can be rewritten as: a....Ch. 1 - The number 1,000,000 is what power of 10? a. 106...Ch. 1 - What exponent or power of ten would you use to...Ch. 1 - Express 0.0562 in exponential notation. a....Ch. 1 - Write the correct answer correct number of...Ch. 1 - Prob. 1.133ECh. 1 - The percentage of oxygen by weight in Al2(SO4)3...Ch. 1 - Prob. 1.135ECh. 1 - The density of gold (Au) is 19.3g/cm3 and that of...
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