MOLECULAR NATURE OF MATTER 7/E LL W/AC
7th Edition
ISBN: 9781119664796
Author: JESPERSEN
Publisher: WILEY
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Textbook Question
Chapter 0, Problem 19RQ
Where in an atom is nearly all of its mass concentrated? Explain your answer in terms of the particles that contribute to this mass.
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 0 Solutions
MOLECULAR NATURE OF MATTER 7/E LL W/AC
Ch. 0 - Practice Exercise 0.1
Using the chapter titles...Ch. 0 - Prob. 2PECh. 0 - Prob. 3PECh. 0 - Prob. 4PECh. 0 - Prob. 5PECh. 0 - Prob. 6PECh. 0 - Prob. 7PECh. 0 - Prob. 8PECh. 0 - Prob. 9PECh. 0 - Practice Exercise 0.10 Aluminum atoms have a mass...
Ch. 0 - Practice Exercise 0.11 How much heavier is the...Ch. 0 - Practice Exercise 0.12 The definition of the size...Ch. 0 - Practice Exercise 0.13 Naturally occurring boron...Ch. 0 - Practice Exercise 0.14
Neon, the gas used in neon...Ch. 0 - Prob. 1RQCh. 0 - 0.2 Knowing what we know today, which of the...Ch. 0 - 0.3 In what ways does the atomic theory affect the...Ch. 0 - Shake a few crystals of salt into your hand and...Ch. 0 - Are there any examples of crystals in nature that...Ch. 0 - 0.6 Heat is one form of energy. If a reaction...Ch. 0 - Can you think of a chemical reaction that starts...Ch. 0 - 0.8 Some large biological molecules rely on...Ch. 0 - 0.9 What elements were formed (a) during the first...Ch. 0 - Prob. 10RQCh. 0 - 0.11 What is the predominant element in the solar...Ch. 0 - Prob. 12RQCh. 0 - What physical factors caused elements and minerals...Ch. 0 - Is this separation still occurring on the earth?Ch. 0 - 0.15 What measuring devices did early chemists...Ch. 0 - 0.16 In your own words, describe how Daltons...Ch. 0 - Which of the laws of chemical combination is used...Ch. 0 - Prob. 18RQCh. 0 - Where in an atom is nearly all of its mass...Ch. 0 - What is a nucleon? Which ones have we studied?Ch. 0 - 0.21 How was the charge-to-mass ratio of the...Ch. 0 - 0.22 How did Robert Millikan determine the charge...Ch. 0 - How was the proton discovered?Ch. 0 - What experiment did Rutherford carry out to...Ch. 0 - Why dont we count the electrons when determining...Ch. 0 - Define the terms atomic number and mass number....Ch. 0 - Prob. 27RQCh. 0 - Write the symbols of the isotopes that contain the...Ch. 0 - What is wrong with the following statement? The...Ch. 0 - 0.30 The atomic number of silver, Ag, is 47 and it...Ch. 0 - A certain element X forms a compound with oxygen...Ch. 0 - Nitrogen reacts with a metal to form a compound in...Ch. 0 - Give the numbers of neutrons, protons, and...Ch. 0 - 0.34 Give the numbers of electrons, protons, and...Ch. 0 - Iodine-131 is used to treat overactive thyroids;...Ch. 0 - Prob. 36RQCh. 0 - 0.37 One chemical substance in natural gas is a...Ch. 0 - 0.38 Carbon tetrachloride contains one carbon and...Ch. 0 - If an atom of carbon-12 had been assigned a...Ch. 0 - 0.40 One atom of has a mass that is 9.0754 times...Ch. 0 - Naturally occurring copper is composed of 69.17%...Ch. 0 - Naturally occurring magnesium (one of the elements...Ch. 0 - N2O is often called nitrous oxide or laughing gas,...Ch. 0 - An element has 24 protons in its nucleus. (a)...Ch. 0 - Iron is composed of four isotopes with the...Ch. 0 - 0.46 What color are the protons, neutrons, and...Ch. 0 - 0.47 Immediately after the big bang, helium and...Ch. 0 - Prob. 48RQCh. 0 - Scientists often validate measurements, such as...Ch. 0 - Sir James Chadwick, discovered the neutron. The...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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