ZOO 445 Data for Problem 2 squitet 180 160 140 120 100 80 60 40 20 10 9 4 3 2 дот HP-30-195 ppm Relative Intensity 100 20 20 40 150 60 m/z 70 80 90 100 HOUSE &
ZOO 445 Data for Problem 2 squitet 180 160 140 120 100 80 60 40 20 10 9 4 3 2 дот HP-30-195 ppm Relative Intensity 100 20 20 40 150 60 m/z 70 80 90 100 HOUSE &
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![Data for Problem 2
ZOO
180 150
120
140
100
80
770
дом
-8
60
40 20
10
9
a
5
015
100
80
Relative Intensity
8
ส
20
20
40
50
ppm
septet
3
2
60
70
80
90
100
m/z](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbe568b77-9516-46bb-9514-8e734fc88ab1%2Fdde20b2b-7940-4a6d-a0a0-32aa45cd6cac%2Fnux665m_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Data for Problem 2
ZOO
180 150
120
140
100
80
770
дом
-8
60
40 20
10
9
a
5
015
100
80
Relative Intensity
8
ส
20
20
40
50
ppm
septet
3
2
60
70
80
90
100
m/z
![2. The mass spectrum, infrared spectrum, and 'H and 13C NMR spectra for a particular compound are given on
the next page. The molecular formula contains one oxygen, with the remainder carbon and hydrogen. Use these data to
identify the structure of the compound. (Hint: Use the mass spectrum to determine the molecular formula. Use the
infrared spectrum to rule in/rule out functional groups. Use the NMR spectra to determine the structure.) Once you have
identified the structure, draw it in the space below and explain, for each spectrum, what about those data is important in
confirming that you have chosen the correct molecule.
3.
Use your knowledge of approximate 'H NMR chemical shifts and spin-spin coupling to sketch the NMR
spectrum of the molecule 4-ethoxybenzoic acid. Assume that the chemical shifts of the two types of hydrogens on the
ring are different. You need not be explicit about the size of the coupling constants. Simply show the correct number of
peaks for each signal.
CH3CH,O
OH
2
1
0
6
4
12 11
10
9
7](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbe568b77-9516-46bb-9514-8e734fc88ab1%2Fdde20b2b-7940-4a6d-a0a0-32aa45cd6cac%2Fvqyp3no_processed.jpeg&w=3840&q=75)
Transcribed Image Text:2. The mass spectrum, infrared spectrum, and 'H and 13C NMR spectra for a particular compound are given on
the next page. The molecular formula contains one oxygen, with the remainder carbon and hydrogen. Use these data to
identify the structure of the compound. (Hint: Use the mass spectrum to determine the molecular formula. Use the
infrared spectrum to rule in/rule out functional groups. Use the NMR spectra to determine the structure.) Once you have
identified the structure, draw it in the space below and explain, for each spectrum, what about those data is important in
confirming that you have chosen the correct molecule.
3.
Use your knowledge of approximate 'H NMR chemical shifts and spin-spin coupling to sketch the NMR
spectrum of the molecule 4-ethoxybenzoic acid. Assume that the chemical shifts of the two types of hydrogens on the
ring are different. You need not be explicit about the size of the coupling constants. Simply show the correct number of
peaks for each signal.
CH3CH,O
OH
2
1
0
6
4
12 11
10
9
7
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