(Z)-3-methyl- pent-2 - ene is reacted with Br2 in CH3OH, as shown in the reaction scheme below.Complete the structure for one stereoisomer for the minor regioisomer formed in this reaction, including stereochemistry where appropriate. Draw both the wedged and dashed bonds at each stereogenic carbon atom.
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- Draw and name ethers andheterocyclic ethers, includingepoxides. Explain the trends intheir boiling points, solubilities,and solvent propertiesAlkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two O Hint in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. The first step of the reaction, hydroboration, involves addition of BH, to the double bond, with -BH, attached to one carbon and hydrogen Be sure to draw hydrogens on oxygen, where applicable. attached to the other. Consider both Rings the regioselectivity and the Select Draw More Erase stereochemistry of this addition. H Diborane, B,H,, is a source of borane, BH,, and can be used 1. B2H6, interchangeably. Diglyme is a solvent. diglyme 2. H2О2, НО", The product or products of the reaction are characterized as being O S. O racemic. O achiral. O R,S (and/or S,R). O R. O S,S. O R.R. O diastereomers.Complete the following: Stereochemistry, enantio-, and regioselectivity are important. CrO3, H2SO4 a) OH Bromination of an alcohol (Sn2) type EtO₂C CO₂Et b) b) d) H3CO type NH2 a) b) H3CO type a) b) OH g) type CN CI h) acetone Swern Oxidation type type CO₂H type Доно i) Me3SICI, Imidazole OSiMe3 Et3N, CH2Cl2 Br type a) Mg°, THF Br j) b); H3O+ H2SO4 (H+) MeOH OMe type type
- Draw the structure of the product formed in the reaction of an epoxide with cthoxide ion. If more than one stcroochemical product is possiblc, draw only onc isomer. Clkarly indicate stercochemistry by drawing a wodged bond, a dashed boond and two in-plane bonds per chiral carbon. Draw Ringa More Select Erese cH 1. CH,CH,0 Na* 2. H*, CH,CH,OH The product(s) of the reaction are characterized as being O RS. O S.S. O R. O S. O achiral. O R.R. O racemic,Draw all of the substitution and elimination products formed from thegiven alkyl halide with each reagent: (a) CH3OH; (b) KOH. Indicate thestereochemistry around the stereogenic centers present in the products,as well as the mechanism by which each product is formed.Compound A, C₂H₁ reacts with 1 molar equivalent(s) of hydrogen upon catalytic hydrogenation. A undergoes reaction with ozone, followed by 2n treatment, to give i O CH₂CCH₂CH₂CH₂CH₂CH₂CH₂ Propose a structure for A • You do not have to consider stereochemistry You do not have to explicitly draw Hatoms In IF ChemDoodie Previous
- NoneWhat is more stable acetate (CH3COO-) or ethoxide (CH3CH2O-)? In three words or less explain your choice:Draw the alkene that would react with the reagent given to account for the product formed. ? + H₂O H₂SO4 CH3 CH3CCH3 OH You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. Sn [F ChemDoodleⓇ
- a) H₂ Pd C-C -H and -H + A-B For the following reagents, indicate the following: a) what is added accross the double bond; b) is the addition stereoselective/stereospecific? If yes, do A and B add syn or anti?; c) draw the product, with relevant stereochemistry, when the reagent system shown is reacted with 1-methylcyclopentene. The answer to the first reagent system is shown below. (i) b) yes, syn addition | | -C-C- (achiral, stereochem. not observable) | I A B (ii) a) 1) 9-BBN 2) H₂O2, NaOH(aq) b)Reaction of Zn/Hg; HCI ( Clemmensen conditions) with CH3CH2C(O)C6H5 forms ____ as the product. (a) CH3CHCHC6H5 (b) CH3CH2COOH and C6H5COOH (c) CH3CH2CH2OH and C6H5OH (d) CH3CH2CH(OH)C6H5 (e) CH3CH2CH2C6H5Draw the alkene that would react with the reagent given to account for the product formed. ? + H₂O H₂SO4 CH3 CH3 CHCCH3 OH CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. Sn [F ChemDoodle