You should be able to graph data. Especially data that you just "make up". Let's make up some data for the work of a reversible vs. irreversible process. a. For a reversible process, work is: ∆w=−nRT∙ln( Vf/Vi) You have 0.25 mole of gas at a temperature of 298 K at an initial volume of 6.113 L. Please make a graph of work vs. final volume, which spans say 1 L to 20 L in 0.1 L increments. b. On the same graph, plot the irreversible work: ∆w = −Pext • (Vf - Vi) . Note that the external pressure must match the final volume. For example, if the final volume is 20 L, then Pext must be 31 kPa for PV=nRT to work. Thus, plot: ∆w = - (nRT/ Vf) • (Vf - Vi) where the final volume spans say 1L to 20 L in 0.1 L increments on the same graph in pt. a.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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You should be able to graph data. Especially data that you just "make up". Let's make up some data for the work of a reversible vs. irreversible process.
a. For a reversible process, work is:
∆w=−nRT∙ln( Vf/Vi)
You have 0.25 mole of gas at a temperature of 298 K at an initial volume of 6.113 L. Please make a graph of work vs. final volume, which spans say 1 L to 20 L in 0.1 L increments.


b. On the same graph, plot the irreversible work: ∆w = −Pext • (Vf - Vi) . Note that the external pressure must match the final volume. For example, if the final volume is 20 L, then Pext must be 31 kPa for PV=nRT to work. Thus, plot:
∆w = - (nRT/ Vf) • (Vf - Vi)
where the final volume spans say 1L to 20 L in 0.1 L increments on the same graph in pt. a.

Expert Solution
Step 1

To plot a graph of reversible work done and irreversible work done for a isothermal process versus the final volume of the gas. 

we are provided with 0.25 mol of a gas with initial volume equals to 6.113 L and the temperature equals to 298 K

The final volume varies from 1 L to 20 L with a span of 0.1 L increments. 

 

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