You are planning to carry out a reaction that produces hydroxide ion. For the reaction to take place at a constant pH, it will be buffered at pH = 4.2. Would it be better to use a formic acid/formate buffer or an acetic acid/acetate buffer? (Note: The pKa of formic acid = 3.75 and the pKa of acetic acid = 4.76.)

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.18P: If the G for a reaction is 4.5 kcal/mol at 298 K, what is the Keq for this reaction? What is the...
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You are planning to carry out a reaction that produces hydroxide ion. For the reaction to take place at a constant pH, it will be buffered at pH = 4.2. Would it be better to use a formic acid/formate buffer or an acetic acid/acetate buffer? (Note: The pKa of formic acid = 3.75 and the pKa of acetic acid = 4.76.)

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