You are given an electrochemical cell where the chemical reaction involves a silver complex. A silver metal bar is used as the positive electrode. The electrochemical potential for this cell is given by E=EºAg+/Ag-0.0592(volts)*log(1/[Ag+]) For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20 volts. Find the silver electrode potential EºAg+/Ag. This same cell from (a) is used to measure the electrochemical potential for a new silver complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver concentration for this new silver complex at equilibrium?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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You are given an electrochemical cell where the chemical reaction involves a silver complex. A silver metal bar is used as the positive electrode. The electrochemical potential for this cell is given by

E=EºAg+/Ag-0.0592(volts)*log(1/[Ag+])

  1. For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20 volts. Find the silver electrode potential EºAg+/Ag.
  2. This same cell from (a) is used to measure the electrochemical potential for a new silver complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver concentration for this new silver complex at equilibrium?
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