Consider the following cell: Mn(s) | MnBr2(0.046 M) || CuBr(0.024 M) | Cu(s) a) Using the standard reduction potentials table, search for the appropriate half reactions that add to the reaction of this full cell. What are the values of the standard potentials of the half cells? E°, = E°. = V b) Calculate the standard potential of the full cell. E° = V c) Calculate the equilibrium constant of the full cellI. K= x 10A
Consider the following cell: Mn(s) | MnBr2(0.046 M) || CuBr(0.024 M) | Cu(s) a) Using the standard reduction potentials table, search for the appropriate half reactions that add to the reaction of this full cell. What are the values of the standard potentials of the half cells? E°, = E°. = V b) Calculate the standard potential of the full cell. E° = V c) Calculate the equilibrium constant of the full cellI. K= x 10A
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Manganese
MnO, + 4H* + 3e¯ =MnO2(s) + 2H2O
Mn+ + e= Mn²+
Mno, + 8H* + 5e¯ = Mn²+ + 4H2O
Mn2O3(s) + 6H* + 2e¯= 2MN²* + 3H,O
MnO,(s) + 4H* + 2e¯=Mn²+ + 2H,O
Mn(EDTA)¯ + e¯=Mn(EDTA)²-
MnO, + e¯ = MnO
3Mn,O3(s) + H,0 + 2e¯=2Mn;O,(8) + 20H¯
Mn;04(s) + 4H;0 + 2e¯ =3Mn(OH)2(s) + 20H"
1.692
-0.671
1.56
1.8
1.507
-0.646
-0.926
1.485
1.230
-0.609
0.825
-1.10
0.56
0.002
-0.352
-2.05
-1.256
-1.61
Mn2+
Mn(OH)2(8) + 2e¯=Mn(s) + 20H¯
- 2e¯ =Mn(s)
-1.182
-1.129
-1.565
-1.10
Copper
Cu* + e= Cu(s)
Cu²+ + 2e¯ = Cu(s)
Cu²+ + e Cu"
CuCl(s) + e¯= Cu(s) + Cl¯
Cu(IO3)2(s) + 2e¯=Cu(s) + 2IO,
Cu(ethylenediamine), + e¯=Cu(s) + 2 ethylenediamine
CuI(s) + e¯= Cu(s) + I¯
Cu(EDTA)²- + 2e¯=Cu(s) + EDTA“-
Cu(OH)2(s) + 2e¯=Cu(s) + 20H'
Cu(CN), + e¯= Cu(s) + 2CN
CuCN(s) + e¯=Cu(s) + CN
0.518
0.339
0.161
0.137
-0.079
-0.119
-0.185
-0.216
-0.222
-0.429
-0.639
Bromine
Bro, + 2H* + 2e¯=BrO, + H2O
HOBR + H* + e¯=}Br2(1) + H,0
Bro, + 6H* + 5e¯ =Br>(1) + 3H2O
Br2(aq) + 2e¯ = 2Br
Br,(1) + 2e¯= 2Br
Br, + 2e= 3Br
Bro + H2O + 2e¯=Br + 20H™
Bro, + 3H,0 + 6e¯=Br + 60H
1.745
-0.511
1.584
-0.75
1.513
1.098
1.078
1.062
0.766
-0.419
-0.499
-0.611
-0.512
-0.94
0.613
-1.287

Transcribed Image Text:Consider the following cell:
Mn(s) | MnBr2(0.046 M) || CuBr(0.024 M) | Cu(s)
a) Using the standard reduction potentials table, search for the appropriate half reactions that add to the reaction of this full cell. What are the values of the standard potentials of the half cells?
E°, =
V
E°- =
b) Calculate the standard potential of the full cell.
E° =
V
c) Calculate the equilibrium constant of the full cell.
K =
x 10^
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