y 23.26 Indicate the coordination number and the oxidation num- ber of the metal for each of the following complexes: (a) K3[Co(CN)6] 6) (b) Na2[CdBr4] (c) [Pt(en)3](ClO4)4 (d) [Co(en)2(C204)]* (e) NH4[Cr(NH3)2(NCS)4] (f) [Cu(bipy)2I]I Common Ligands in Coordination Chemistry (Section 23.3) 23.27 For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) ethylamine, CH,CH,NH2, (b) trimethylphosphine, P(CH,), (c) carbonate, CO3" , (d) ethane, C,H,. 3? 23.28 For each of the following polydentate ligands, determine (i) the maximum number of coordination sites that the ligand can occupy on a single metal ion and (ii) the number and type of donor atoms in the ligand: (a) ethylenediamine (en), (h) hinvridin 2-)

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section22.4: Structures Of Coordination Compounds
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26: a,b,c,

y
23.26 Indicate the coordination number and the oxidation num-
ber of the metal for each of the following complexes:
(a) K3[Co(CN)6]
6)
(b) Na2[CdBr4]
(c) [Pt(en)3](ClO4)4
(d) [Co(en)2(C204)]*
(e) NH4[Cr(NH3)2(NCS)4]
(f) [Cu(bipy)2I]I
Common Ligands in Coordination Chemistry
(Section 23.3)
23.27 For each of the following molecules or polyatomic ions,
draw the Lewis structure and indicate if it can act as a
monodentate ligand, a bidentate ligand, or is unlikely
to act as a ligand at all: (a) ethylamine, CH,CH,NH2,
(b) trimethylphosphine, P(CH,), (c) carbonate, CO3" ,
(d) ethane, C,H,.
3?
23.28 For each of the following polydentate ligands, determine (i)
the maximum number of coordination sites that the ligand
can occupy on a single metal ion and (ii) the number and
type of donor atoms in the ligand: (a) ethylenediamine
(en), (h) hinvridin
2-)
Transcribed Image Text:y 23.26 Indicate the coordination number and the oxidation num- ber of the metal for each of the following complexes: (a) K3[Co(CN)6] 6) (b) Na2[CdBr4] (c) [Pt(en)3](ClO4)4 (d) [Co(en)2(C204)]* (e) NH4[Cr(NH3)2(NCS)4] (f) [Cu(bipy)2I]I Common Ligands in Coordination Chemistry (Section 23.3) 23.27 For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) ethylamine, CH,CH,NH2, (b) trimethylphosphine, P(CH,), (c) carbonate, CO3" , (d) ethane, C,H,. 3? 23.28 For each of the following polydentate ligands, determine (i) the maximum number of coordination sites that the ligand can occupy on a single metal ion and (ii) the number and type of donor atoms in the ligand: (a) ethylenediamine (en), (h) hinvridin 2-)
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