Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:C. Nomenclature of molecules with functional groups:
Now we can slowly begin to introduce functional groups on the chain. When functional
groups are involved in the molecule, there are divided into three groups for naming. As
indicated from the chart in Figure 1. When functional groups are involved, heteroatoms
get introduced in the chain. Thus, the root compound is chosen to include the
functional group; sometimes even when there is a longer chain present.
1.
WS-2.8: Provide systematic names for the following compounds.
2.
3.
4.
i. Functional groups indicated by "prefix-only": These group will always be low in
priority and always be listed as prefix substituents.
a. Alkyl
b. Alkoxy
5.
c. Halogen (Fluoro-, Chloro-, Bromo- & lodo-)
d. Nitro
e. Azido
a
ax
a
Br
F
6.
7.
8.
9.
8
10.
Br
Br Br
CI F Br
-NO₂
Br
Br
Br

Transcribed Image Text:11.
1.
2.
3.
WS-2.9: Provide systematic names for the following compounds.
4.
5.
12.
ii. Functional groups indicated by "suffix-only": These functional groups will always
be present in the suffix of the molecule.
a. Alkene
b. Alkyne
●
Since a double bond (alkene) or a triple bond (alkyne) are formed between two
carbons in the parent chain, the locator in the name is the number of the first
carbon that makes the double bond following the rule of obtaining the lowest
numbering for the suffix functional group.
Prefixes like di-, tri-, etc., can be used to indicate multiple unsaturated bonds in
the molecule.
When alkene and alkyne are both present in the same molecule, the name will
be arranged alphabetically. The numbering will still be chosen to obtain the
lowest numbering combination. Thus, the numbering decides the priority
when they are both present in the same molecule.
zaha
6.
7.
8.
9.
10.
Br. Br
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