Write structure, in line or condensed notation, for the major products) of the following reactions (include stereochemistry where appropriate): Br2 H₂O
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- Predict the products of halogenations, oxidations, reductions, and cleavages of alkenes, including the orientation (regiochemistry) and the stereochemistry of the reaction.Write the structures of the following organic halogen compounds :(i) 4-tert-Butyl-3-iodoheptane(ii) 4-Bromo-3-methylpent-2-eneCompounds with more than one hydroxyl group can react with thionyl chloride differently from simple alcohols. In the reaction with thionyl chloride, the butane-1,2-diol gave a single organic product with 85% yield, according to the following balanced equation: (Suggest a reasonable structure for this product and make a mechanism to justify your reasoning using curved arrows to describe the motion of electrons)
- Draw the structure of the predominant form of CF3CH2OH (pK a = 12.4) at pH = 6.An unknown hydrocarbon Q has a formula C6H12. Q reacts with osmium tetroxide to give a diol R when oxidized with KMnQ4 in an acidic medium Q gives two products. One product is propanoic acid and the other is ketone S. Provide reaction equations to identify the possible structures of Q, R and S.The rate law for addition of Br2 to an alkene is first orderin Br2 and first order in the alkene. Does this informationsuggest that the mechanism of addition of Br2 to analkene proceeds in the same manner as for addition of HBr?Explain.
- from each. a) b) c) Predict the product of the following reactions. Provide the major organic product Br Br Br →→ Li CN acetone Na₂S(b) (1-chloromethyl)cyclopentane, CeH11CI reacts with aqueous sodium hydroxide, NaOH to produce a primary alcohol AA. When CeH11Cl is added with magnesium, Mg in ether, an organometallic compound BB is formed. When compound BB reacts with ethanal, CH3CHO, a secondary alcohol cCis formed. The molecular structure of CeH11Cl is given below. (1-klorometil)siklopentana, CoH1,CI bertindak balas dengan akues natrium hidroksida, NaOH bagi menghasilkan satu alkohol primer AA. Apabila CeH11CI ditambah dengan magnesium, Mg dalam eter, sebatian organologam BB terbentuk. Apabila sebatian BB bertindak balas dengan etanal, CH;CHO, satu alkohol sekunder CC dihasilkan. Struktur molekul bagi CsH11CI diberikan di bawah. .CI (1-chloromethyl)cyclopentane (i) Draw the structural formula for compound AA through Cc. Lukiskan formula struktur bagi sebatian AA sehingga C. (ii) What is the type of reaction to produce compound AA? Apakah jenis tindak balas untuk menghasilkan sebatian AA?4. Propose structures for alkenes that yield the following products on treatment with acidic KMnO4: (a) (CH3)2C=0 + CO2 (b) 2 equiv CH3CH2CO2H 5. Show the structure of Teflon by drawing several repeating units. The monomer unit is tetrafluoroethylene, F2C=CF2. 6. Draw resonance structures for the following species: (a) CH2 + (b) H. :0: (c) H. H H
- Predict the products of additions, oxidations, reductions, and cleavages of alkynes, including the orientation of the reaction (regiochemistry) and the stereochemistry.a Complete the following reaction of a disulfide with a reducing agent. What is the structure of the organic product (of which two moles are formed)? CH3CH2-S-S-CH2CH3 + 2(H) · C P орy aste CH4 ChemDoodle®We have a hydrocarbon, C16H26. The compound has two triple bonds and the acids produced by ozonolysis are CH3(CH2)4CO2H and H2OCCH2CO2H. What is a likely structure for this hydrocarbon?
