With a gas thermometer, T can be measured...(A). from less than 10 K(B). from 273.15 K(C). from 100°C (at p = 1 atm).(D). from the T of the triple point of water
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With a gas thermometer, T can be measured...
(A). from less than 10 K
(B). from 273.15 K
(C). from 100°C (at p = 1 atm).
(D). from the T of the triple point of water
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- At the critical point for carbon dioxide, the substance is very far from being an ideal gas. Prove this statement by calculating the density of an ideal gas in g/cm3 at the conditions of the critical point and comparing it with the experimental value. Compute the experimental value from the fact that a mole of CO2 at its critical point occupies 94 cm3.Please don't provide handwritten solution ....(a) Use the following data for NH3 (g) at T = 273 K to evaluate B2P (T). (Here Z is the compressibility factor, PV/RT). P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 0.70 Note: You will need to fit this data to a least-squares line. (b) At standard temperature (273.15 K), the density of O₂ varies with pressure as indicated in the table below: P (bar) 0.25331 0.50663 0.75994 1.01325 Z-1 1.519 x 10-4 3.038 x 10-4 4.557x 10-4 6.071 x 10-4 7.583 x 10-4 9.002 x 10-4 1.0551 x 10-3 2 p(g/L) 0.356985 0.714154 1.071485 1.428962 Use this data to find the second virial coefficient, B2v, of oxygen. Note that mo2 = 31.9988 Daltons. (Hint: It will be useful to determine the molar volume from each value of p.)
- A gas mixture contains 4.5 mol Br, and 33.1 mol F,. (a) Compute the mole fraction of Br, in the mixture. (b) The mixture is heated above 150°C and starts to react to give BrFs: Br2(g) + 5 F2(g) –→ 2 BrF;(g) At a certain point in the reaction, 2.2 mol BrF5 is present. Determine the mole fraction of Br2 in the mixture at that point.4. (a) Determine the reduced pressure (P,), volume (V,), and temperature (T, ) for a 50 L sample of water at 23 bar and 400 K. For H2O gas, Te = 647.14 K, P. = 220.64 bar, and Vc=55.95 L. (b) Determine the pressure, volume and temperature for a sample of hydrogen which is in a corresponding state with the H2O in part (a). For hydrogen, Te = 32.98 K, Pc = 12.93 bar and mc =64.20 L.What is the temperature in K of 0.795 mole of neon in a 2.00 L vessel at 4.32 bar? R = 0.08314 L･bar/mol･K.
- For ethane at 298.15 K, B = -186 cm³mol-¹ and C= 1.06x104 cm'mol². Use the formula B PVm = RT [1 1+ + Vm V2 m to calculate the pressure of 28.8 g of ethane in a 999 cm³ container at 298.15 K and the amount of atm in which it is far from the ideal value.Under constant-pressure conditions a sample of hydrogen gas initially at 47°C (320K) and 6700 mL is heated to 122°C (395K). What is the final volume?An open-end mercury manometer is to be used to measure the pressure in an apparatus containing a vapor that reacts with mercury. A 10-cm layer of silicon oil (SG = 0:92) is placed on top of the mercury in the arm attached to the apparatus. Atmospheric pressure is 765 mm Hg.(a) If the level of mercury in the open end is 365 mm below the mercury level in the other arm, what is the pressure (mm Hg) in the apparatus?(b) When the instrumentation specialist was deciding on a liquid to put in the manometer, she listed several properties the fluid should have and eventually selected silicon oil. What might the listed properties have been?
- 5(6) Calculate the molar volume of carbon dioxide at 400 K and 30 atm, given that the second virial coefficient (B) for CO2 is -0.0605 L•mol-1. Compare the result with that obtained using the ideal-gas law.An experiment is conducted in which a quantity of H2(g) is chemically generated in a closed headspace of volume V1 at absolute temperature T1, thereby raising the total pressure from Pa (the initial air pressure) to Pf (the total final pressure of H2(g) + air). Compose an algebraic expression for the volume (V2) that this sample of H2(g) would occupy if it were isolated (pure -- i.e. no air) at absolute temperature T2 and partial pressure P2. Note that your expression may contain no other variables than those given above, namely: V1, T1, T2, Pa, Pf, and P2. A) V2 = Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP. B) VM =
