Why does acetone [(CH3)2C=O, dipole moment = 2.69 D] have a larger dipole moment than phosgene [Cl₂C=O, dipole moment = 1.17 D]? Note: electronegativities C = 2.5, Cl = 3.2, O = 3.5, H = 2.2 Select one: O A. In phosgene, the resultant of the C-Cl bond dipole moments is opposite to and partially cancels the C=O dipole moment. In acetone, the resultant of the C-H bond dipole moments (although small) adds to the C=O dipole moment. O B. Phosgene has a tetrahedral geometry while acetone possesses a trigonal geometry. OC. The C-H bond dipole moments of acetone are greater in magnitude than C-Cl bond dipole moments of phosgene. O D. In phosgene the C-Cl bond dipoles cancel out each other.

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Chapter1: Chemical Foundations
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### Why does acetone \((\text{CH}_3)_2\text{C}=\text{O}, \text{dipole moment} = 2.69 \, \text{D}\) have a larger dipole moment than phosgene \([\text{Cl}_2\text{C}=\text{O}, \text{dipole moment} = 1.17 \, \text{D}]\)?

**Note:** Electronegativity values  
- Carbon (C) = 2.5  
- Chlorine (Cl) = 3.2  
- Oxygen (O) = 3.5  
- Hydrogen (H) = 2.2  

**Select one:**

- **A.** In phosgene, the resultant of the C-Cl bond dipole moments is opposite to and partially cancels the C=O dipole moment. In acetone, the resultant of the C-H bond dipole moments (although small) adds to the C=O dipole moment.

- **B.** Phosgene has a tetrahedral geometry while acetone possesses a trigonal geometry.

- **C.** The C-H bond dipole moments of acetone are greater in magnitude than C-Cl bond dipole moments of phosgene.

- **D.** In phosgene the C-Cl bond dipoles cancel out each other.
Transcribed Image Text:### Why does acetone \((\text{CH}_3)_2\text{C}=\text{O}, \text{dipole moment} = 2.69 \, \text{D}\) have a larger dipole moment than phosgene \([\text{Cl}_2\text{C}=\text{O}, \text{dipole moment} = 1.17 \, \text{D}]\)? **Note:** Electronegativity values - Carbon (C) = 2.5 - Chlorine (Cl) = 3.2 - Oxygen (O) = 3.5 - Hydrogen (H) = 2.2 **Select one:** - **A.** In phosgene, the resultant of the C-Cl bond dipole moments is opposite to and partially cancels the C=O dipole moment. In acetone, the resultant of the C-H bond dipole moments (although small) adds to the C=O dipole moment. - **B.** Phosgene has a tetrahedral geometry while acetone possesses a trigonal geometry. - **C.** The C-H bond dipole moments of acetone are greater in magnitude than C-Cl bond dipole moments of phosgene. - **D.** In phosgene the C-Cl bond dipoles cancel out each other.
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