Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Write the products that will occur in the following reactions. Show homo lumo orbitals for all reactions.
NOT: ISI = Heat
![**Reactions of Benzene in Organic Chemistry**
In this educational segment, we are focusing on two reactions involving benzene. Benzene is a cyclic hydrocarbon with the molecular formula \( C_6H_6 \) and is known for its stable ring structure with alternating double bonds.
### Reaction a)
**Reactants:**
1. Benzene (\( C_6H_6 \))
2. Hexachloroacetone (\( \text{CCl}_3\text{COCl} \))
3. Zinc (Zn), used in the presence of a solvent which will be referred to as ISI (not specified).
**Reaction:**
Benzene reacts with hexachloroacetone in the presence of zinc and an unspecified solvent (ISI).
**Diagram Description:**
- Benzene is represented by a hexagonal ring with alternating double bonds.
- Hexachloroacetone is represented with three chlorine atoms attached to a carbon that is double-bonded to an oxygen atom and bonded to a carbon-chlorine group.
### Reaction b)
**Reactants:**
1. Benzene (\( C_6H_6 \))
2. Acrolein or Propenal (\( \text{CH}_2=\text{CHCHO} \))
3. An unspecified solvent (ISI).
**Reaction:**
Benzene reacts with acrolein (or propenal) in the presence of an unspecified solvent (ISI).
**Diagram Description:**
- Benzene is shown again with its common hexagonal representation.
- Acrolein is depicted with a three-carbon chain, where the first two carbons have a double bond (CH2=CH) and the last carbon is doubly bonded to oxygen (CHO).
These reactions illustrate advanced organic transformation processes involving benzene and other reagents, potentially used in synthesizing more complex aromatic compounds. Further details regarding the mechanisms, product structures, and specific solvent (ISI) used would depend on the specific experimental conditions and targets in the reaction setups.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F7eb16600-8f07-40f7-854e-83024f28a747%2Faeaeab24-f647-481a-a2b1-a7564b3f6c1c%2Fogo4jwf_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Reactions of Benzene in Organic Chemistry**
In this educational segment, we are focusing on two reactions involving benzene. Benzene is a cyclic hydrocarbon with the molecular formula \( C_6H_6 \) and is known for its stable ring structure with alternating double bonds.
### Reaction a)
**Reactants:**
1. Benzene (\( C_6H_6 \))
2. Hexachloroacetone (\( \text{CCl}_3\text{COCl} \))
3. Zinc (Zn), used in the presence of a solvent which will be referred to as ISI (not specified).
**Reaction:**
Benzene reacts with hexachloroacetone in the presence of zinc and an unspecified solvent (ISI).
**Diagram Description:**
- Benzene is represented by a hexagonal ring with alternating double bonds.
- Hexachloroacetone is represented with three chlorine atoms attached to a carbon that is double-bonded to an oxygen atom and bonded to a carbon-chlorine group.
### Reaction b)
**Reactants:**
1. Benzene (\( C_6H_6 \))
2. Acrolein or Propenal (\( \text{CH}_2=\text{CHCHO} \))
3. An unspecified solvent (ISI).
**Reaction:**
Benzene reacts with acrolein (or propenal) in the presence of an unspecified solvent (ISI).
**Diagram Description:**
- Benzene is shown again with its common hexagonal representation.
- Acrolein is depicted with a three-carbon chain, where the first two carbons have a double bond (CH2=CH) and the last carbon is doubly bonded to oxygen (CHO).
These reactions illustrate advanced organic transformation processes involving benzene and other reagents, potentially used in synthesizing more complex aromatic compounds. Further details regarding the mechanisms, product structures, and specific solvent (ISI) used would depend on the specific experimental conditions and targets in the reaction setups.
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