Which of the following structures corresponds to the attached 1H-NMR spectrum?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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(59) Which of the following structures corresponds to the attached 1H-NMR spectrum?

C12H17 NO
1
(broad singlet)
8
7
-CH₂
6
1.4
--G-CH₂ 1.7
L-CH₂
-C-C-H
PPM
TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR
Type of proton Approximate chemical shift (ppm) Type of proton
(CH)),Si
-CH₂
-CH₂-
-CH-
R-O-CH₂
R-C-CH₂
R-C-C-H
0.9
1.3
2.1
2.3
24
3.3
4.7
5
5.3
2
(triplet)
tr
RNH₂
CI-C-H
ROH
ArOH
H
ܐ
-OH
"The values are approximate because they are affected by neighboring substituents.
3
3
(singlet)
2
(quartet) 2
(triplet)
6.5-8
Approximate chemical shift (ppm)
9.0-10
2.5-4
2.5-4
2
445
variable, 1.5-4
variable, 2-5
variable, 4-7
3
(triplet)
variable, 10-12
Transcribed Image Text:C12H17 NO 1 (broad singlet) 8 7 -CH₂ 6 1.4 --G-CH₂ 1.7 L-CH₂ -C-C-H PPM TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR Type of proton Approximate chemical shift (ppm) Type of proton (CH)),Si -CH₂ -CH₂- -CH- R-O-CH₂ R-C-CH₂ R-C-C-H 0.9 1.3 2.1 2.3 24 3.3 4.7 5 5.3 2 (triplet) tr RNH₂ CI-C-H ROH ArOH H ܐ -OH "The values are approximate because they are affected by neighboring substituents. 3 3 (singlet) 2 (quartet) 2 (triplet) 6.5-8 Approximate chemical shift (ppm) 9.0-10 2.5-4 2.5-4 2 445 variable, 1.5-4 variable, 2-5 variable, 4-7 3 (triplet) variable, 10-12
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Transcribed Image Text:ZI IZ ZI IZ
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