Which of the following pairs of ions represent isoelectronic species? A) Mg2* and O² B) K+ and Li+ C) Ca2+ and F- D) Fe2* and S² E) Al3+ and CI
Which of the following pairs of ions represent isoelectronic species? A) Mg2* and O² B) K+ and Li+ C) Ca2+ and F- D) Fe2* and S² E) Al3+ and CI
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question:**
Which of the following pairs of ions represent isoelectronic species?
**Options:**
A) Mg²⁺ and O²⁻
B) K⁺ and Li⁺
C) Ca²⁺ and F⁻
D) Fe²⁺ and S²⁻
E) Al³⁺ and Cl⁻
**Explanation:**
**Isoelectronic species** are atoms, molecules, or ions that have the same number of electrons. This property allows them to exhibit similar electronic configurations and often similar chemical properties with respect to electron-carrying behaviors, even if they are different species.
To determine which pairs are isoelectronic, count the electrons in each ion and compare:
- **Mg²⁺:** Magnesium originally has 12 electrons. Losing two electrons leaves it with 10 electrons.
- **O²⁻:** Oxygen originally has 8 electrons. Gaining two electrons gives it 10 electrons.
- **K⁺:** Potassium originally has 19 electrons. Losing one electron leaves it with 18 electrons.
- **Li⁺:** Lithium originally has 3 electrons. Losing one electron leaves it with 2 electrons.
- **Ca²⁺:** Calcium originally has 20 electrons. Losing two electrons leaves it with 18 electrons.
- **F⁻:** Fluorine originally has 9 electrons. Gaining one electron gives it 10 electrons.
- **Fe²⁺:** Iron originally has 26 electrons. Losing two electrons leaves it with 24 electrons.
- **S²⁻:** Sulfur originally has 16 electrons. Gaining two electrons gives it 18 electrons.
- **Al³⁺:** Aluminum originally has 13 electrons. Losing three electrons leaves it with 10 electrons.
- **Cl⁻:** Chlorine originally has 17 electrons. Gaining one electron gives it 18 electrons.
By matching the electron counts, we see that **option A, Mg²⁺ and O²⁻, are isoelectronic** as they each have 10 electrons.
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