Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Identifying Tertiary Alkyl Halides
When learning about alkyl halides, it's important to understand their classification based on the carbon atom to which the halogen (in this case, bromine) is attached. Alkyl halides can be primary, secondary, or tertiary. A tertiary alkyl halide has the halogen atom attached to a carbon that is itself connected to three other carbon atoms.
**Question:**
Which of the following is a tertiary alkyl halide?
1. ○ 1-Bromo-2-methylpropane
2. ○ 2-Bromo-2-methylpropane
3. ○ 2-Bromopropane
4. ○ 1-Bromobutane
**Explanation:**
- **1-Bromo-2-methylpropane**: In this compound, the bromine atom is attached to a primary carbon (a carbon attached to only two other carbons and a hydrogen).
- **2-Bromo-2-methylpropane**: Here, the bromine atom is attached to a tertiary carbon (a carbon attached to three other carbons).
- **2-Bromopropane**: In this compound, the bromine is attached to a secondary carbon (a carbon attached to two other carbons).
- **1-Bromobutane**: The bromine in this compound is attached to a primary carbon.
For educational purposes:
The correct answer is **2-Bromo-2-methylpropane**. It is the only option where the bromine atom is attached to a tertiary carbon, making it a tertiary alkyl halide.
Understanding the structure and classification of alkyl halides is fundamental in organic chemistry, as they often serve as key intermediates in synthetic reactions.
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