Which alkene cannot be converted into an alkyl bromide with HBr, ROOR, hv, A? 1 11 IV A. B. C. D. E. All react Which synthetic route is best to give the major product shown below. ? x Xx OH A. 1. BH3; 2. H₂O2, NaOH; 3. HBr; 4. CH3CO₂H B. 1. Br2, 2. NaCCH; H₂, Lindlar's; 3. 03; 4. H₂O C. 1. NBS, hv, A; 2. H₂, Pd; 3. NaO₂CCH3 D. 1. NBS, hv, A; 2. NaCCH; 3. H₂, Pd; 4. O3; 5. H₂O E. 1. NBS, hv, A; 2. H₂, Pd; 3. NaCCH; 4. O3; 5. H₂O Which synthetic route is best for the transformation shown below? OH ? OH A. 1. H₂SO4/heat; 2. HgOAc2, H₂O; 3. NaBH4 B. 1. HBr; 2. NaOH, DMSO C. 1. TsCl, pyr; 2. NaOH, DMSO D. 1. TsCl, pyr; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH E. 1. H₂SO4/heat; 2. BH3-THF; 3. H₂O2, NaOH
Which alkene cannot be converted into an alkyl bromide with HBr, ROOR, hv, A? 1 11 IV A. B. C. D. E. All react Which synthetic route is best to give the major product shown below. ? x Xx OH A. 1. BH3; 2. H₂O2, NaOH; 3. HBr; 4. CH3CO₂H B. 1. Br2, 2. NaCCH; H₂, Lindlar's; 3. 03; 4. H₂O C. 1. NBS, hv, A; 2. H₂, Pd; 3. NaO₂CCH3 D. 1. NBS, hv, A; 2. NaCCH; 3. H₂, Pd; 4. O3; 5. H₂O E. 1. NBS, hv, A; 2. H₂, Pd; 3. NaCCH; 4. O3; 5. H₂O Which synthetic route is best for the transformation shown below? OH ? OH A. 1. H₂SO4/heat; 2. HgOAc2, H₂O; 3. NaBH4 B. 1. HBr; 2. NaOH, DMSO C. 1. TsCl, pyr; 2. NaOH, DMSO D. 1. TsCl, pyr; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH E. 1. H₂SO4/heat; 2. BH3-THF; 3. H₂O2, NaOH
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:Which alkene cannot be converted into an alkyl bromide with HBr, ROOR, hv, A?
III
IV
A.
B.
C.
D.
E. All react
Which synthetic route is best to give the major product shown below.
?
x
XA
OH
A. 1. BH3; 2. H₂O2, NaOH; 3. HBr; 4. CH3CO₂H
B. 1. Br₂, 2. NaCCH; H₂, Lindlar's; 3. O3; 4. H₂O
C. 1. NBS, hv, A; 2. H₂, Pd; 3. NaO₂CCH3
D. 1. NBS, hv, A; 2. NaCCH; 3. H₂2, Pd; 4. O3; 5. H₂O
E. 1. NBS, hv, A; 2. H₂, Pd; 3. NaCCH; 4. 03; 5. H₂O
Which synthetic route is best for the transformation shown below?
OH
?
OH
A. 1. H₂SO4/heat; 2. HgOAC2, H₂O; 3. NaBH4
B. 1. HBr; 2. NaOH, DMSO
C. 1. TsCl, pyr; 2. NaOH, DMSO
D. 1. TsCl, pyr; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH
E. 1. H₂SO4/heat; 2. BH3-THF; 3. H₂O2, NaOH
=B
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