When water is the solvent, the pKa of acetic acid (CH3CO2H) is 4.75, but when DMSO is the solvent, the pKa is 12.6.Explain why. Hint: Review Section 2.9 and consider the ability of each solvent to solvate cations and anions.
When water is the solvent, the pKa of acetic acid (CH3CO2H) is 4.75, but when DMSO is the solvent, the pKa is 12.6.Explain why. Hint: Review Section 2.9 and consider the ability of each solvent to solvate cations and anions.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.18P: If the G for a reaction is 4.5 kcal/mol at 298 K, what is the Keq for this reaction? What is the...
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When water is the solvent, the pKa of acetic acid (CH3CO2H) is 4.75, but when DMSO is the solvent, the pKa is 12.6.Explain why.
Hint: Review Section 2.9 and consider the ability of each solvent to solvate cations and anions.
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