Dicarboxylic acids have two dissociation constants, one for the initial dissociation into a rnonoanion and one for the second dissociation into a dianion . For oxalic acid, HO2C-CO.H, the first ionization constant has pKaj = 1.2 and the second ionization constant has pKaz = 4.2. Why is the second carboxyl group so much less acidic than the first?
Dicarboxylic acids have two dissociation constants, one for the initial dissociation into a rnonoanion and one for the second dissociation into a dianion . For oxalic acid, HO2C-CO.H, the first ionization constant has pKaj = 1.2 and the second ionization constant has pKaz = 4.2. Why is the second carboxyl group so much less acidic than the first?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Dicarboxylic acids have two dissociation constants, one for the initial dissociation into a rnonoanion and one
for the second dissociation into a dianion . For oxalic acid, HO,C-CO,H, the first ionization constant has
pKaj = 1.2 and the second ionization constant has pKaz = 4.2. Why is the second carboxyl group so much less
acidic than the first?
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