When the Pd(0)-catalyzed reactions covered in this chapter are run with a slight pres- sure of carbon monoxide, a ketone is often created as the product. For example, the following Stille coupling conditions with added CO give the product shown. Write a mechanism for how this reaction could occur using the organometallic mechanistic steps introduced in this chapter, along with new steps that would be required in this transformation. Hint: CO can coordinate to Pd and insert into Pd-C bonds. n-BugSn Pd(PPH3)4, CO

When the Pd(0)-catalyzed reactions covered in this chapter are run with a slight pres- sure of carbon monoxide, a ketone is often created as the product. For example, the following Stille coupling conditions with added CO give the product shown. Write a mechanism for how this reaction could occur using the organometallic mechanistic steps introduced in this chapter, along with new steps that would be required in this transformation. Hint: CO can coordinate to Pd and insert into Pd-C bonds. n-BugSn Pd(PPH3)4, CO

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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