When the difference in pH across the membrane of a glass electrode at 25 °C is 3.75 pH units, how much voltage is generated by the gradient? A. Not Enough Information to Determine B. 222 mV O C. 180 mV OD. 273 mV E. 0.222 mV F. 0.273 mV O G. 3.75 mV
When the difference in pH across the membrane of a glass electrode at 25 °C is 3.75 pH units, how much voltage is generated by the gradient? A. Not Enough Information to Determine B. 222 mV O C. 180 mV OD. 273 mV E. 0.222 mV F. 0.273 mV O G. 3.75 mV
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Question:
When the difference in pH across the membrane of a glass electrode at 25 °C is 3.75 pH units, how much voltage is generated by the pH gradient?
### Options:
- A. Not Enough Information to Determine
- B. 222 mV
- C. 180 mV
- D. 273 mV
- E. 0.222 mV
- F. 0.273 mV
- G. 3.75 mV
### Explanation:
This question is about calculating the voltage generated by a pH difference across a membrane. The relationship between pH difference and voltage can be determined using the Nernst equation for an ion-selective electrode. At 25 °C, the theoretical change in voltage per pH unit for a hydrogen ion concentration cell is approximately 59.16 mV. To find out the voltage generated by a pH difference of 3.75, you would calculate:
\[ \text{Voltage (mV)} = 59.16 \times \text{pH difference} \]
Substitute the given difference:
\[ \text{Voltage (mV)} = 59.16 \times 3.75 \]
Calculating this will give the correct answer.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F70774868-ea05-4fa3-ae6c-7ea4e68d506a%2F5045625b-6df3-4b5f-9d51-b98bb5c35484%2Fksieguu_processed.png&w=3840&q=75)
Transcribed Image Text:### Question:
When the difference in pH across the membrane of a glass electrode at 25 °C is 3.75 pH units, how much voltage is generated by the pH gradient?
### Options:
- A. Not Enough Information to Determine
- B. 222 mV
- C. 180 mV
- D. 273 mV
- E. 0.222 mV
- F. 0.273 mV
- G. 3.75 mV
### Explanation:
This question is about calculating the voltage generated by a pH difference across a membrane. The relationship between pH difference and voltage can be determined using the Nernst equation for an ion-selective electrode. At 25 °C, the theoretical change in voltage per pH unit for a hydrogen ion concentration cell is approximately 59.16 mV. To find out the voltage generated by a pH difference of 3.75, you would calculate:
\[ \text{Voltage (mV)} = 59.16 \times \text{pH difference} \]
Substitute the given difference:
\[ \text{Voltage (mV)} = 59.16 \times 3.75 \]
Calculating this will give the correct answer.
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